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Oil Sands Environmental Management Bibliography

The Cumulative Environmental Management Association (CEMA)partnered with the Oil Sands Research and Information Network (OSRIN) to create the new Oil Sands Environmental Management Bibliography, which includes documents relevant to the environmental management of oil sands development in Alberta. The majority of the documents focus on the mineable oil sands in the Athabasca deposit, though some documents relate to in-situ developments. This bibliography was last updated in November 2014.

Trend analysis of historical ambient air monitoring data in Edmonton and Fort McKay, Alberta

Year of Publication: 2000

Abstract:
Collecting and analyzing ambient air monitoring data is valuable for understanding the state of air quality and addressing perceptions and concerns about it relates to health impacts. Results of trend analysis of ambient air data at two Alberta monitoring stations, i.e., Edmonton and Fort McKay, were presented. Pollutant concentrations and hourly exceedance frequencies corresponding to cumulative frequency values were examined. Trends include SO2, NO2, O3 etc. Changes or lack of changes observed in air quality do not necessarily provide an indication of what may happen over the long-term. The decreasing trends observed for PM2.5, SO2, etc. may be related to better emission controls from automobiles. This is an abstract of a paper presented at the AWMA's 99th Annual Conference and Exhibition (New Orleans, LA 6/20-23/2006).

Trottier Energy Futures: Greenhouse gas emissions from the Canadian oil and gas sector

Authors Evans, R. L., & Bryant T.
Year of Publication: 2013

Abstract:
In developing low carbon scenarios for Canada, it is important to understand the role of the oil and gas sector as a major contributor to greenhouse gas emissions. The Canadian Energy Systems Simulator model has been chosen to provide estimates of current and future energy use and GHG emissions. This report is divided into two main sections examining GHG emissions from oil and gas production in Canada.

Typha latifolia plant performance and stand biomass in wetlands affected by surface oil sands mining

Year of Publication: 2013

Abstract:
Stand productivity of the dominant macrophyte Typha latifolia may be constrained by salinity and pollution in the oil sands wetlands of northern Alberta. We compared the performance and stand biomass of T. latifolia plants established in oil sands industrial wetlands (directly exposed to byproduct processed materials), on-site indirectly-affected, and off-site natural wetlands. We studied T. latifolia physiology (gas exchange, leaf fluorescence), morphology, leaf chemistry, and stand biomass. Oil sands plants had lower stomatal conductance than plants in natural wetlands resulting in lower transpiration but unaffected net photosynthesis rates. Oil sands plants had smaller and lower numbers of green leaves than natural wetlands plants. T. latifolia stands established in oil sands wetlands had lower aboveground and total biomass compared to natural wetlands. Despite water chemistry differences, T. latifolia plant performance did not differ between oil sands wetlands types. However, there was a lower total stand biomass in industrial than in indirectly-affected wetlands. T. latifolia had an unaltered photosynthetic activity in the oil sands wetlands allowing for the maintenance of persistent plant stands. However, T. latifolia growth restrictions and a lower stand biomass in the oil sands wetlands probably compromise long-term reclamation objectives focused on the accumulation of organic sediment and peat.

Uncertainty-based modelling of soil chemical response to acidic deposition

Year of Publication: 2011

Abstract:
An analysis of weathering rate uncertainty was conducted with the PROFILE model to support the first uncertainty-based application of the Model of Acidification of Groundwater Catchments (MAGIC) in the region. In addition, the calibration and application of the Very Simple Dynamic (VSD) model was carried out to investigate the influence of different cation exchange models on dynamic simulations of soil chemistry. The primary outcomes of this research are summarized below: 1) Weathering rates exhibited large variability within the seven soil series investigated 2) Despite uncertainties in soil properties, Mildred and Firebag soils have consistently low weathering potential (maximum rates were below 0.4 keg ha-1yr-1) 3) An automated Monte-Carlo based application of MAGIC was developed for application to a single site (plot or polygon) 4) The uncertainty-based MAGIC framework has the capacity to predict the likelihood of base saturation and base cation to aluminium ratio reaching the critical thresholds specified under the Acid Deposition Management Framework 5) Comparison of VSD simulations conducted using Gaines-Thomas and Gapon soil-soil solution cation exchange models suggests a negligible influence of the exchange model on the frequency of critical threshold exceedence.

Unconventional bridges over troubled water - lessons to be learned from the Canadian oil sands as the United States moves to develop the natural gas of the Marcellus shale play

Authors Jefferies, C.
Year of Publication: 2012

Abstract:
As North America's energy demands grow in the face of diminishing conventional fossil fuel resources, unconventional oil and gas figures to play an increasingly important role. This article assesses two important unconventional fossil fuel deposits, namely the oil sands located in Alberta, Canada and the Marcellus Shale gas located in America's Appalachian region as well as the importance of properly crafted regulatory regimes that safeguard another critical natural resource - fresh water. Development of unconventional fossil fuels requires considerable quantities of fresh water for extraction and produces substantial quantities of contaminated wastewater as a byproduct. This analysis addresses the importance of unconventional fossil fuels, compares the two resources in terms of extraction and water impact, highlights the weaknesses in the regulatory regimes in Alberta and the Marcellus Shale states, and proposes federal intervention and/or regional management as a possible solution, as justified by traditional theories of regulation (i.e., the externalization of pollution and race to the bottom theory). Commercial oil sands extraction has been ongoing for at least forty years and, above all, the Canadian experience demonstrates the importance of properly considered regulation and regional monitoring prior to accelerated development in the Marcellus Shale gas play.

Understanding and developing new methods for treating oil sands tailings

Authors Kaura, A.
Year of Publication: 2014

Abstract:
Management of oil sands tailings from bitumen extraction operations remains a challenge for mineable oil sands producers. Promoting fine solids settling in tailings ponds is key to treating oil sands tailings. Present study explores two methods of tailings treatment – ATA process and polymer assisted CT process. ATA (Anchor-Tether-Activator) process involves anchor of particles usually coarse solids with tethering polymer and adding an activator polymer to tailings slurry. MF1011 was used as activator polymer, while in-house synthesized Al-PAM and commercially available pDADMAC were used as tethering polymers. Both Al-PAM and pDADMAC were able to produce non-segregated tailings, but the initial settling rate was higher with the use of Al-PAM while the turbidity of supernatant was lowest with the use of pDADMAC. A novel method for treating oil sands tailings using only coarse sand and tethered polymer pDADMAC was developed. This new process is capable of producing clear water for extraction and sediment bed of high yield stresses at significantly reduced consumption of polymers.

Understanding biogeochemical gradients of sulfur iron and carbon in an oil sands tailings pond

Year of Publication: 2014

Abstract:
Oil sands tailings ponds in Alberta (Canada) are strongly stratified ecosystems structured in an upper water layer and underlying mud layers that harbour a diversity of microorganisms, contributing to hydrocarbon degradation and elemental cycling. Until now not much is known about the biogeochemistry of the ponds and their spatial structure is not well explored yet. An understanding of microbial activity and community composition is important, in particular, in order to determine potential effects on pond properties and long term development. Therefore, the purpose of the present study was to identify reactive zones of iron, carbon and sulfur cycling in an active tailings pond, by comparing biogeochemical data along two depth profiles. For both profiles a zone of intense sulfur cycling was substantiated by maxima of: (a) dissolved and solid sulfides (b) sulfate reduction rates and thiosulfate oxidation potentials (c) viable counts of sulfate reducers and relative abundances of functional genes. In addition, methanogenesis and microbial iron reduction were shown to be important electron accepting processes in the ponds. All processes coexisted in a zone of intense elemental cycling at a depth of 1–4 m below the water-mud interface, where fresh tailings are likely to accumulate. Microbial activity and biomass decreased with depth, where tailings had higher age and density. While the upper mud layers were influenced by the presence of different archaea, the microbial communities showed an increased presence of bacterial species at depth. Insights from qPCR, 35S radiotracer technique and stable isotope analysis mirrored some differences between the profiles, regarding sulfur and carbon cycling. Despite this, both profiles showed remarkably similar patterns of microbial community composition and activity, revealing a good reproducibility of biogeochemical cycling within a few meters.

Understanding the Canadian oil sands industry's greenhouse gas emissions

Year of Publication: 2009

Abstract:
The magnitude of Canada’s oil sands reserves, their rapidly expanding and energy intensive production, combined with existing and upcoming greenhouse gas (GHG) emissions regulations motivate an evaluation of oil sands-derived fuel production from a life cycle perspective. Thirteen studies of GHG emissions associated with oil sands operations are reviewed. The production of synthetic crude oil (SCO) through surface mining and upgrading (SM&Up) or in situ and upgrading (IS&Up) processes is reported to result in emissions ranging from 62 to 164 and 99 to 176 kgCO2eq/bbl SCO, respectively (or 9.2–26.5 and 16.2–28.7 gCO2eq MJ−1 SCO, respectively), compared to 27–58 kgCO2eq/bbl (4.5–9.6 gCO2eq MJ−1) of crude for conventional oil production. The difference in emissions intensity between SCO and conventional crude production is primarily due to higher energy requirements for extracting bitumen and upgrading it into SCO. On a ‘well-to-wheel’ basis, GHG emissions associated with producing reformulated gasoline from oil sands with current SM&Up, IS&Up, and in situ (without upgrading) technologies are 260–320, 320–350, and 270–340 gCO2eq km−1, respectively, compared to 250–280 gCO2eq km−1 for production from conventional oil. Some variation between studies is expected due to differences in methods, technologies studied, and operating choices. However, the magnitude of the differences presented suggests that a consensus on the characterization of life cycle emissions of the oil sands industry has yet to be reached in the public literature. Recommendations are given for future studies for informing industry and government decision making.

Understanding toxicity at the watershed scale: Design of the Syncrude Sandhill Fen Watershed Research Project

Authors Wytrykush, C.
Year of Publication: 2010

Abstract:
Fens are peat-accumulating wetlands with a water table consisting of mineral-rich ground or surface water. This study discussed the construction of a fen-type reclaimed wetland constructed in a post-mining oil sands landscape. Syncrude Canada's Sandhill fen watershed project represents the first attempt at constructing a fen wetland in the oil sands region. The wetland and its watershed will be constructed on a soft tailings deposit. The design basis for the fen and watershed was developed by a team of researchers and scientists. The aim of the fen design was to control the salinity caused by tailings consolidation and seepage over time. Methods of mitigating potentially toxic effects from salinity were discussed.

Understanding water-based bitumen extraction from Athabasca oil sands

Year of Publication: 2004

Abstract:
The current state of knowledge on the fundamentals of bitumen recovery from Athabasca oil sands using water-based extraction methods is reviewed. Instead of investigating bitumen extraction as a black box, the bitumen extraction process has been discussed and analyzed as individual steps: Oil sand lump size reduction, bitumen liberation, aeration, flotation and interactions among the different components that make up an oil sand slurry. With the development and adoption of advanced analytical instrumentations, our understanding of bitumen extraction at each individual step has been extended from the macroscopic scale down to the molecular level. How to improve bitumen recovery and bitumen froth quality from poor processing ores is still a future challenge in oil sands processing.

Use of a (quantitative) structure-activity relationship [(Q)SAR] model to predict the toxicity of naphthenic acids

Year of Publication: 2010

Abstract:
Naphthenic acids (NA) are a complex mixture of carboxylic acids that are natural constituents of oil sand found in north-eastern Alberta, Canada. NA are released and concentrated in the alkaline water used in the extraction of bitumen from oil sand sediment. NA have been identified as the principal toxic components of oil sands process-affected water (OSPW), and microbial degradation of lower molecular weight (MW) NA decreases the toxicity of NA mixtures in OSPW. Analysis by proton nuclear magnetic resonance spectroscopy indicated that larger, more cyclic NA contain greater carboxylic acid content, thereby decreasing their hydrophobicity and acute toxicity in comparison to lower MW NA. The relationship between the acute toxicity of NA and hydrophobicity suggests that narcosis is the probable mode of acute toxic action. The applicability of a (quantitative) structure-activity relationship [(Q)SAR] model to accurately predict the toxicity of NA-like surrogates was investigated. The U.S. Environmental Protection Agency (EPA) ECOSAR model predicted the toxicity of NA-like surrogates with acceptable accuracy in comparison to observed toxicity values from Vibrio fischeri and Daphnia magna assays, indicating that the model has potential to serve as a prioritization tool for identifying NA structures likely to produce an increased toxicity. Investigating NA of equal MW, the ECOSAR model predicted increased toxic potency for NA containing fewer carbon rings. Furthermore, NA structures with a linear grouping of carbon rings had a greater predicted toxic potency than structures containing carbon rings in a clustered grouping.

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