Skip To Content

Oil Sands Environmental Management Bibliography

The Cumulative Environmental Management Association (CEMA)partnered with the Oil Sands Research and Information Network (OSRIN) to create the new Oil Sands Environmental Management Bibliography, which includes documents relevant to the environmental management of oil sands development in Alberta. The majority of the documents focus on the mineable oil sands in the Athabasca deposit, though some documents relate to in-situ developments. This bibliography was last updated in November 2014.

Three-dimensional characterization of the total dissolved solids concentration and stable isotope composition of porewater extracted from Athabasca oil sands drill core

Year of Publication: 2014

Abstract:
Total dissolved solids (TDS) concentrations in McMurray Formation waters range from 220 to 280 000 mg/L in the Athabasca Oil Sands Region (AOSR) (Cowie et al., 2014). The observed variability in TDS concentrations within a reservoir or across a lease area influences measurements of resistivity that are required for resource assessment. Here we present a robust, low-cost method to characterize the geochemical composition of reservoir pore fluids from drill core derived porewater. The methods reveals the heterogeneity of TDS concentrations and the stable isotope compositions (δ2H, δ18O) of reservoir porewater, both vertically within a core, and laterally across a field. Analysis of water samples extracted directly from drill core provides a significant advance in the ability to characterize the properties of reservoir porewater, but requires corrections to account for drilling fluid contamination. Our new technique utilizes two end-member mixing relationships between the stable isotope compositions of drilling fluids and formation waters from multiple samples within a single reservoir, and does not require GeoConvention 2014: FOCUS 1 measurement of drilling fluids to calculate formation water properties. The new method revealed that water derived from drill cores in several preliminary reservoirs had significant variability in TDS (860 to 45 000 mg/L), δ2H (−172 to −149‰) and δ18O (−22.4 to −19.3‰). These values are consistent with regional trends in formation water salinity and stable isotope composition, and illustrate the wide range of TDS values that can be found in McMurray Formation waters. A detailed characterization of the Suncor-Firebag lease area revealed both lateral and vertical heterogeneity in TDS and stable isotope compositions of McMurray Formation waters, thus providing a three-dimensional approach to water characterization within these oil sands reservoirs. This new methodology provides a tool to understand the origin and movement of reservoir water due to natural groundwater flow, and may be able to detect anthropogenic influence by steam injection. Additionally, novel in-situ extraction technologies that utilize electromagnetic or radio wave heating systems may also benefit from detailed characterization of aqueous reservoir fluids to accurately determine the resistivity and water properties of the reservoir.

Threshold considerations and wetland reclamation in Alberta's mineable oil sands

Authors Foote, L.
Year of Publication: 2012

Abstract:
Oil sand extraction in Alberta, Canada is a multibillion dollar industry operating over 143 km² of open pit mining and 4600 km² of other bitumen strata in northern boreal forests. Oil production contributes to Canada-wide GDP, creates socio-cultural problems, provides energy exports and employment, and carries environmental risks regarding long-term reclamation uncertainties. Of particular concern are the implications for wetlands and water supply management. Mining of oil sands is very attractive because proven reserves of known quality occur in an accessible, politically stable environment with existing infrastructure and an estimated 5.5 billion extractable barrels to be mined over the next five decades. Extraction occurs under a set of limiting factors or thresholds including: limited social tolerance at local to international levels for externalities of oil sand production; water demands > availability; limited natural gas supplies for oil processing leading to proposals for hydroelectric dams and nuclear reactors to be constructed; difficulties in reclaiming sufficient habitat area to replace those lost. Replacement of the 85 km² of peat-forming wetlands forecast to be destroyed appears unlikely. Over 840 billion liters of toxic fluid byproducts are currently held in 170 km² of open reservoirs without any known process to purify this water in meaningful time frames even as some of it leaches into adjacent lands and rivers. Costs for wetland reclamation are high with estimates of $4 to $13 billion, or about 6% of the net profits generated from mining those sites. This raises a social equity question of how much reclamation is appropriate. Time frames for economic, political, and ecological actions are not well aligned. Local people on or near mine sites have had to change their area use for decades and have been affected by industrial development. Examining mining effects to estimate thresholds of biophysical realities, time scales, economic allocations, and social tolerance helps to contextualize the needs for decision making and relevant policy formation as a way of constructively reconciling production with governing safeguards to the environment and citizens.

Threshold detection values of potential fish tainting substances from oil sands wastewaters

Year of Publication: 1988

Abstract:
Chemical compounds associated with oil sands extraction and upgrading operations have been implicated in the tainting of the Athabasca River fishery, a commercial and subsistence fishery for local natives. Selected contaminants found in oil sands wastewaters, and judged to be candidate tainting compounds, were spiked in walleye flesh and subjected to screening odour and taste detection by a trained sensory panel. Twelve compounds were screened and 8 were pursued for determination of detection thresholds based upon 3 separate sessions with a minimum of 9 panelists. Taint detection threshold values ranging from 0.09 mg/kg for benzothiophene to 12.2 mg/kg for 2,6-dimethylnaphthalene were established. These values will assist in determining the significance of analytically determined concentrations of these compounds in fish flesh.

Time domain reflectometry (TDR) oil sands tailings water content measurements: Texture effect

Year of Publication: 2012

Abstract:
Temperature, solute, texture and thixotropic effects on time domain reflectometry (TDR) measurements of water content in oil sands tailings are investigated. Results indicate that TDR water content measurements are influenced by temperature, residual bitumen and percent clay in the tailings. Apparent dielectric constant (Ka) correction of 0.03–0.10/°C is required to account temperature effect. The Ka-volumetric water content relationships of slurry significantly differ from the commonly used Topp’s calibration equation. The age of the tailings and the addition of Phosphogypsum did not influence TDR water content measurements.

Tolerance mechanisms of black spruce (Picea mariana) seedlings exposed to saline oil sands tailings

Authors Redfield, E. B.
Year of Publication: 2000

Abstract:
Petroleum extraction from oil sands in Alberta produces tailings with high ion concentrations (Na+, Cl−, and SO42−). Composite tailings retain water, leaving portions of deposits waterlogged. A potential species for revegetation of tailings is black spruce (Picea mariana (Mill.) B.S.P.). It is flood tolerant, so identification of salt tolerance characteristics could allow screening of planting stock. Salt affects plants by inducing water deficit, and ion toxicity. This study used controlled environment and field experiments to examine relationships between drought tolerance and salt tolerance in black spruce. Plant responses to water deficit were examined by measuring water relations parameters derived from Pressure-Volume curves. Parameters indicating drought tolerance were predictors of injury caused by salt stress. These included: lower relative water content at the turgor loss point; higher relative water content of the symplast; lower osmotic potential at the turgor loss point; lower maximum bulk modulus of elasticity; and higher osmotic amplitude for turgor maintenance.

Total analysis of mineral wastes containing bitumen solvent water and solids

Authors Majid, A., & Sparks B. D.
Year of Publication: 1984

Abstract:
Compared with the existing methods of analyses a quick and more reliable procedure has been developed to determine the bitumen, solvent, water and solids content of mineral wastes, in order to serve efficiently both plant operations and research needs. Bitumen and hydrocarbon solvent in the samples are extracted using solvents that do not absorb in the CH₃ group region of the ¹H NMR spectrum. Bitumen is then determined spectrophotometrically, and the process solvent by quantitative ¹H NMR. Water is dissolved in methanol and subsequently determined using a Karl Fischer titrator. Solids are measured gravimetrically. This procedure was used to analyse mineral tailings from the centrifuge stage of the hot water process for the extraction of bitumen from oil sands. Results for all four components; bitumen, process solvent, water and solids, had relative standard deviations much lower than the ones obtained using a modified Dean-Stark method. Mineral agglomerates obtained after the extraction of bitumen from oil sands using the solvent extration-spherical agglomeration method, were also analyzed by both methods. As a result of compaction occurring during solids agglomeration, complete extraction of bitumen by the Dean-Stark method could not be achieved. Extraction of bitumen and precision of results were much improved for agglomerated samples using the proposed method of analysis which is amenable to wastes containing solids, water, bitumen and solvent in any proportion.

Toward culturally appropriate consultation: An approach for Fort McKay First Nation

Authors McKillop, J. A.
Year of Publication: 2002

Abstract:
Resource extraction from the traditional lands of Aboriginal peoples without appropriate consideration for traditional land use activities has transformed social and cultural structures, compromised economies, and restricted access to resources. Industrial intrusion into the traditional lands of Fort McKay First Nation, located within the Athabasca oil sands region of northern Alberta, reveals the need to develop an effective approach for consultation that addresses the implications of resource extraction for traditional activities and associated social and cultural values. This MDP establishes that existing frameworks do not recognize the rights of Aboriginal people and do not meet the standards for consultation set by the courts. Current approaches to the assessment of impacts on traditional land use are inadequate due to their lack of recognition of what landscapes are most important to the community. A Culturally Significant Ecosystem (CSE) approach is developed to define patterns of resource harvesting according to intensity of use, an approach that is founded in the values and interests of community in the use of natural resources and geographic distribution of harvesting activities. A more appropriate development assessment framework is proposed, one that relies on a CSE approach, the development of a community-based environmental management strategy, and is cognizant of the rights of Aboriginal peoples. This framework represents a movement from consultation toward true participation of the community, and recognizes both the desire and ability of Aboriginal people to make decisions about what affects their lives and their livelihoods.

Toward designing a sustainable watershed reclamation strategy

Authors Keshta, N.
Year of Publication: 2010

Abstract:
Oil sands mining results in significant disturbances to natural ecosystems when soil and overburden materials are removed and stockpiled to provide access to mined materials. The mining process must be followed by land reclamation, whereby disturbed landscapes are recovered with the intent to replicate the performance of natural watersheds. Modeling hydrological processes in reclaimed landscapes is essential to assess the hydrological performance of the reclamation strategies as well as their evolution over time, and requires a reliable and continuous source of input data. In pursuit of simulating the various hydrological processes, such as soil moisture and actual evapotranspiration, a lumped generic system dynamics watershed (GSDW) model has been developed. The validity of the proposed model has been assessed in terms of its capacity to reproduce the hydrological behaviour of both reconstructed and natural watersheds. Data availability is a major challenge that constrains not only the type of models used but also their predictive ability and accuracy. This study evaluates the utility of precipitation and temperature data from the North American Regional Reanalysis (NARR) versus conventional platform data (e.g., meteorological station) for the hydrological modeling. Results indicate NARR data is a suitable alternative to local weather station data for simulating soil moisture patterns and evapotranspiration fluxes despite the high complexity involved in simulating such processes. Initially, the calibrated GSDW model was used along with available historical meteorological records, from both Environment Canada and NARR, to estimate the maximum soil moisture deficit and annual evapotranspiration fluxes. A probabilistic framework was adopted, and frequency curves of the maximum annual moisture deficit values were consequently constructed and used to assess the probability that various reconstructed and natural watersheds would provide the desired moisture demands. The study shows a tendency for the reconstructed watersheds to provide less moisture for evapotranspiration than natural systems. The probabilistic framework could be implemented to integrate information gained from mature natural watersheds (e.g., the natural system canopy) and transfer the results to newly reconstructed systems. Finally, this study provided some insight into the sensitivity of soil moisture patterns and evapotranspiration to possible changes in the projected precipitation and air temperature in the 21st century. Climate scenarios were generated using daily, statistically downscaled precipitation and air temperature outputs from global climate models (CGCM3), under A2 and B1 emission scenarios, to simulate the corresponding soil moisture and evapotranspiration using the GSDW model. Study results suggest a decrease in the maximum annual moisture deficit will occur due to the expected increase in annual precipitation and air temperature patterns, whereas actual evapotranspiration and runoff are more likely to increase.

Towards an integrated oil sands mine plan and composite tailings plan

Year of Publication: 2013

Abstract:
One of the major issues in current oil sands waste management is the lack of a direct link between long-term mine plans and the quantity of the tailings produced downstream. This research is focused on developing a link between the oil sands’ long-term mine plans and the final composite tailings (CT) produced downstream. The objective is to assist in making the oil sands production process comply with the regulations set by the Alberta Energy Resources and Conservation Board (Directive 074). A series of mass-balance relations between the ore tonnage and the final CT tonnage was developed. This was followed by implementing the mass-balance relations with a case study and reporting the CT production schedule from the long-term mine plan. To capture the uncertainties associated with the CT production process, a stochastic simulation model was developed. Finally, sensitivity analysis was carried out to capture the sensitivity of the CT tonnages produced to the fluctuations of the stochastic input variables. The link between the long-term mine schedule and tailings management plan helps mine planners to set a dyke construction schedule and raise the dyke height in each period in accordance with the volume of tailings produced. This research illustrates the uncertainties associated with the amount of CT produced over the mine life. Understanding these uncertainties will lead to improved and sustainable mining and waste management practices in oil sands mining industry.

Towards focused environmental assessment: A new approach to impact scoping for environmental impact assessment

Authors Kennedy, A. J.
Year of Publication: 1992

Abstract:
Impact scoping is the process of identifying important tissues of a proposal and focusing the Environmental Impact Assessment (EIA) on the high priority issues. Although impact scoping in one form or another has been inherent to EIA for some time, discussion of its development and refinement have not been forthcoming. This thesis traces the progression of impact scoping through time and highlights the need for such processes in EIA. A Focused Environmental Assessment (FEA) approach to impact scoping that is suitable for implementation in an EIA is conceptually developed within this research study, and advantages of its use are delineated. FEA is a three staged process than encourages impact scoping through progressive steps including impact identification, assessment, and management planning. FEA combines a suite of EIA methods including: issues matrices, impact hypothesis statements and pathway diagrams, valued ecosystem components, and stakeholder participation sessions, all of which effectively integrateimpact scoping within an EIA process. The FEA is presented in the thesis within a case study context through application of the process to an oil sands mega-project in northeastern Alberta (the OSLO Project). The components and principles of impact scoping are practically demonstrated in this example. The impact identification stage included a work session attended by the FEA study team and the key stakeholders. This work session resulted in a matrix depicting the important environmental issues that require further assessment. Subsequent assessment work sessions resulted in thirty-five integrated environmental impact hypotheses statements and pathways diagrams (representative examples are given in the thesis) that are used by the FEA study team and key stakeholders in the preparation of impact forecasts, and to document residual impacts. The final work session was held with all of those individuals from the previous sessions, to determine the optimal monitoring and mitigation plans for the impacts. To evaluate the FEA the author of this thesis compared the FEA impact scoping process used for the OSLO Project case to EIA impact scoping processes used for other oil sand projects. Five oil sands projects carried out over a ten year period, in northeastern Alberta, were selected for the evaluation. A set of evaluation criteria was devised and indicators for each criterion were evaluated under the key impact scoping components of equity, effectiveness and efficiency. Based mainly on the fact that it is the most recent attempt to formalize and impact scoping process, the OSLO Project attained more evaluation criteria than did the other five oil sands projects. Examples of good impact scoping were also demonstrated in the other EIAs. The attributes of FEA are discussed in detail within the thesis, as well as the capabilities for integration of the FEA approach with selected EIA administrative processes.

Toxic liability: How Albertans could end up paying for oil sands mine reclamation

Year of Publication: 2010

Abstract:
The pace and scale of oil sands mining continues to increase in Alberta despite a poor understanding of the environmental liabilities: costs associated with the environmental impacts throughout the life of a mine. In Toxic Liability, the Pembina Institute has compiled the first public estimate of these liabilities. Over their 30 to 50 years of operation, oil sands mines have had significant environmental impacts, including emissions of greenhouse gases and other pollutants, surface water withdrawals, contamination and disruption of groundwater, toxic seepage from tailings lakes into groundwater, habitat fragmentation and impacts on wildlife. To mitigate some of these impacts, oil sands mining companies are required to reclaim the land that has been disturbed during the mining process. Companies budget to pay for reclamation, which is supposed to occur as a company develops a mine. The cleanup bill for mines is potentially immense. Alberta requires all oil sands mine operators to post a security deposit to fund reclamation in the event an operator is unable or unwilling to pay for reclamation. However, because of the lack of transparency about the true costs of reclamation, the public doesn’t know whether or not the current security deposits are adequate.

Toxicity assessment of collected fractions from an extracted naphthenic acid mixture

Year of Publication: 2009

Abstract:
Recent expansion within the oil sands industry of the Athabasca Basin of Alberta, Canada has led to increased concern regarding process-affected wastewaters produced during bitumen extraction. Naphthenic acids (NAs) have been identified as the primary toxic constituents of oil sands process-affected waters (OSPW) and studies have shown that with time, microbial degradation of lower molecular weight NAs has led to a decrease in observed toxicity. As earlier studies identified the need for an “unequivocal demonstration” of lower molecular weight NAs being the primary contributors to mixture toxicity, a study was initiated to fractionate an extracted NA mixture by molecular weight and to assess each fraction’s toxicity. Successful molecular weight fractionation of a methylated NA mixture was achieved using a Kugelrohr distillation apparatus, in which fractions collected at higher boiling points contained NAs with greater total carbon content as well as greater degree of cyclicity. Assays with Vibrio fischeri bioluminescence (via Microtox assay) revealed that the lowest molecular weight NAs collected had higher potency (EC50: 41.9 ± 2.8 mg l−1) than the highest molecular weight NAs collected (EC50: 64.9 ± 7.4 mg l−1). Although these results support field observations of microbial degradation of low molecular weight NAs decreasing OSPW toxicity, it is not clear why larger NAs, given their greater hydrophobicity, would be less toxic.

Toxicity assessment of oil sands process-affected water using fish cell lines

Authors Sansom, B.
Year of Publication: 2010

Abstract:
Toxicity assessment of large numbers of oil sands process-affected waters (OSPW) are needed in order to reclaim mined oil sands aquatic reclamation scenarios, such as End Pit Lakes (EPLs). Conventional toxicity testing using whole animals can make this process extremely costly, thus alternatives are being sought. A non-lethal bioassay is being developed and validated to aid in supporting reclamation planning. This study employed six fish cell-lines (WF-2, GFSk- S1, RTL-W1, RTgill-W1, FHML, FHMT) in 24h viability assays for rapid fluorometric assessment of cellular integrity and functionality. Eight ml from forty-nine OSPW samples received from Syncrude Canada Ltd. were mixed with 2 ml of 5X concentrated L-15/ex minimal media solution and used to expose cells. After 24h exposure to OSPW samples, significant decreases in cell viability as measured by Alamar blue (AB) were seen in all cell lines for a number of samples. Bioassays were done in blind, but when OSPW chemical composition was revealed there was a consistent correlation between decreasing cell viability and increasing naphthenic acid (NA) concentrations present in the samples. Regression analysis yielded correlation coefficients2 as high as 0.6171 (WF-2 cell line, AB; p<0.0001). NAs have been identified as the chief toxicants in OSPW. Therefore, a fish-cell line bioassay sensitive to fluctuations in NA concentration could be a tool integral to the safe implementation and biomonitoring of wet reclamation landscapes in the Athabasca oil sands region, such as EPLs.

Enter keywords or search terms and press Search

Search this site


Subscribe to the site

Syndicate content

Bookmark and Share