@proceedings {54096,
	title = {Three-dimensional characterization of the total dissolved solids concentration and stable isotope composition of porewater extracted from Athabasca oil sands drill core},
	year = {2014},
	note = {IN: GeoConvention 2014: FOCUS.  },
	pages = {4 pages },
	abstract = {Total dissolved solids (TDS) concentrations in McMurray Formation waters range from 220 to 280 000 mg/L in the Athabasca Oil Sands Region (AOSR) (Cowie et al., 2014). The observed variability in TDS concentrations within a reservoir or across a lease area influences measurements of resistivity that are required for resource assessment. Here we present a robust, low-cost method to characterize the geochemical composition of reservoir pore fluids from drill core derived porewater. The methods reveals the heterogeneity of TDS concentrations and the stable isotope compositions (δ2H, δ18O) of reservoir porewater, both vertically within a core, and laterally across a field. Analysis of water samples extracted directly from drill core provides a significant advance in the ability to characterize the properties of reservoir porewater, but requires corrections to account for drilling fluid contamination. Our new technique utilizes two end-member mixing relationships between the stable isotope compositions of drilling fluids and formation waters from multiple samples within a single reservoir, and does not require
GeoConvention 2014: FOCUS 1
measurement of drilling fluids to calculate formation water properties. The new method revealed that water derived from drill cores in several preliminary reservoirs had significant variability in TDS (860 to 45 000 mg/L), δ2H (-172 to -149{\textperthousand}) and δ18O (-22.4 to -19.3{\textperthousand}). These values are consistent with regional trends in formation water salinity and stable isotope composition, and illustrate the wide range of TDS values that can be found in McMurray Formation waters. A detailed characterization of the Suncor-Firebag lease area revealed both lateral and vertical heterogeneity in TDS and stable isotope compositions of McMurray Formation waters, thus providing a three-dimensional approach to water characterization within these oil sands reservoirs. This new methodology provides a tool to understand the origin and movement of reservoir water due to natural groundwater flow, and may be able to detect anthropogenic influence by steam injection. Additionally, novel in-situ extraction technologies that utilize electromagnetic or radio wave heating systems may also benefit from detailed characterization of aqueous reservoir fluids to accurately determine the resistivity and water properties of the reservoir.},
	keywords = {analytical methodology, groundwater, hydrogeology, salinity, sodicity, Suncor, UofC},
	url = {http://www.geoconvention.com/archives/2014/090_GC2014_Three-dimensional_characterization_of_the_total_dissolved_solids.pdf},
	author = {Cowie, Benjamin R. and James, Bruce and Nightingale, Michael and Mayer, Bernhard}
}
