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Oil Sands Environmental Management Bibliography

The Cumulative Environmental Management Association (CEMA)partnered with the Oil Sands Research and Information Network (OSRIN) to create the new Oil Sands Environmental Management Bibliography, which includes documents relevant to the environmental management of oil sands development in Alberta. The majority of the documents focus on the mineable oil sands in the Athabasca deposit, though some documents relate to in-situ developments. This bibliography was last updated in November 2014.

Microwave treatment of naphthenic acids in water

Year of Publication: 2010

Abstract:
Naphthenic acids (NAs) are natural constituents of bitumen and crude oil, and predominantly obtained as the by-product of petroleum refining with variable composition and ingredients. Naphthenic acids are composed of alkyl-substituted cycloaliphatic carboxylic acids, with smaller amounts of acyclic aliphatic acids. Naphthenic acids become a significant part of the tailings pond water (TPW) after separation from oil sands material. NAs are soluble in water and are concentrated in TPW as a result of caustic oil sands extraction processes. Tailings ponds near the Athabasca oil sands region near Fort McMurray, Alberta, Canada are contaminated with a variety of toxic organic compounds released in industrial effluent from the oil extraction processes. NAs are among the major water contaminants in those regions because of their toxicity and environmental recalcitrance. They may enter surface water systems due to erosion of riverbank oil sands deposits and through groundwater mixing. Significant environmental and regulatory attention has been focused on the naphthenic acids fraction of oil sands material to address these challenges and potential hazards. Biological, chemical, and photolytic treatments of water contaminated with NAs have been studied, but are either time consuming or involve significant capital investment. There is a growing need to develop more efficient and cost-effective treatment methods. Based on existing literature, microwave and photocatalysis for degradation of naphthenic acids in water may be one solution. A knowledge gap exists in determining the effect of microwave energy and/or photocatalysis on the rate and extent of NAs degradation in contaminated water. Part of this work included evaluation of the physical and chemical properties of NAs. Dielectric properties, important for designing a microwave system, were investigated. Effects of temperature, concentration, and frequency of microwaves on the dielectric properties of NA-water mixtures were studied and were used in designing the treatment systems for NAs. Three laboratory scale systems, (1) photocatalysis, (2) microwave, and (3) microwave assisted photocatalysis systems were designed and developed. Experiments were conducted to determine the NA degradation efficiency of these systems for both commercially available Fluka NAs and those extracted from oil sand process water (OSPW). Effects of water source (deionised and river water) and use of TiO2 catalyst in the degradation process, were also investigated. Degradation kinetics for total NAs as well as individual z-family were calculated. Results show that the three developed treatment systems were able to degrade NAs at a faster rate than the methods reported to date. The concentration of higher molecular weight NAs (z = -4 to -12) decreased more significantly than the lower molecular weight NAs in all the three treatment systems. Toxicity assessments of the NAs samples before and after treatment indicated that photocatalysis and microwave assisted photocatalysis systems decreased the toxicity of Fluka and OSPW NAs completely (up to 5 min IC50 v/v > 90%). The microwave system reduced the toxicity of water containing Fluka NAs from high (5 min IC50 v/v = 15.85%) to moderate (5 min IC50 v/v = 36.45%) toxicity. However, a slight increase in toxicity was noted post-treatment in OSPW NAs. Microwave-assisted photocatalysis was the most rapid degradation system for OSPW NA extracts in water with a half-life of 0.56 h in the presence of TiO2. The microwave system degraded OSPW NAs in water at a more moderate half-life of 3.32 h. The photocatalysis system was the slowest with a half-life of 3.99 h under similar conditions. High and ultra high resolution analysis of NA sample, estimations of cost and further efficiency related research of the developed systems to treat water with microbial load along with chemical contaminants are recommended for future work to further validate these treatment systems.

Migration of inconnu (Stenodus leucichthys) and burbot (Lota lota), Slave River and Great Slave Lake, June 1994 to July 1995

Year of Publication: 1996

Abstract:
To determine the timing of movements and relative abundance of burbot, Lota lota, and inconnu, Stenodus leucichthys, on the lower Slave River north of the 60th parallel, we sampled on a regular basis using gillnets from June to November, 1994. Movement patterns in time and space in the Slave River and Great Slave Lake were determined by radio-tagging 24 inconnu and 16 burbot in the fall of 1994. Tracking was carried through the fall of 1994 through to July 1995. Inconnu entered the Slave River system from Great Slave Lake in August and attained peak catch-per-unit-effort (CPUE) during the first two weeks of September. By November they had left the system. Burbot CPUE did not increase substantially, therefore, no discemable pattern of movement was recognized from catches. Radio-tagged inconnu stayed in the Fort Smith area of the river until late October when they migrated out of the system into Great Slave Lake. Migrations in Great Slave Lake appeared to be geographically extensive. From January to the end of August 1995, all inconnu were captured or detected by radio telemetry in Great Slave Lake, only. No inconnu were detected or captured in the Slave River. Extensive floy- tagging programs conducted by the Department of Fisheries and Oceans corroborate these observations for inconnu in Great Slave Lake. Burbot appeared to be relatively sedentary and probably escaped detection by residing in deep holes of the river and the river delta. These movement patterns signify that inconnu may transfer contaminants over a large area including Great Slave Lake whereas burbot would concentrate contaminants locally in the lower Slave River and its delta.

Migratory waterfowl and the Syncrude tar sands lease: A report

Year of Publication: 1973

Abstract:
In the Spring of 1971, the management of Syncrude contacted Renewable Resources Consulting Services regarding assessments of potential ecological impacts on the lease area. As a result, a preliminary investigation of ecological relationships was undertaken in July of 1971. This was followed by other surveys to assess fisheries, wildlife (including waterfowl) and the general ecological conditions of the Boreal Mixedwood Forest Ecosystem in which Lease #17 is located. An attempt was made to identify potential areas of concern during the preliminary investigation of the development. Assessments of potential conflicts between resource extraction operations and the functioning of ecological relationships on the lease area were initiated. These preliminary investigations were not considered to represent quantitative or qualitative statements of ecological impacts, but were made primarily to determine whether or not significant potential problems existed. Objectives of the waterfowl surveys are: 1) To monitor waterfowl migrations through the Syncrude Lease 17 and general area during all seasons of use. 2) To establish the locations and intensity of use. 3) To document the chronology of migration through the area. 4) To determine the key areas used during the migration. 5) To further examine the implications of the Syncrude development upon waterfowl. 6) To suggest mitigative measures, if any, that might be taken.

Mineable oil sands aquifer management and reclamation concept review

Authors Mooder, B.
Year of Publication: 2013

Abstract:
The purpose of the study was to: (1) review aquifer reclamation concepts for the North Athabasca Oil Sands (NAOS) mineable area in northeastern Alberta, Canada, (2) to compile applicable regulations, technologies, and methods for aquifer reclamation, and (3) to provide recommendations to support further development of aquifer reclamation concepts.

Mineralogy and phase transition of oil sands coke ash

Authors Jang, H., & Etsell T. H.
Year of Publication: 2006

Abstract:
Coke obtained from Syncrude and Suncor was investigated to characterize the metals and minerals by ashing it at various temperatures. Samples were collected by high temperature ashing at 100 °C intervals from 400 to 1200 °C. Samples were also obtained from low temperature ashing (LTA) which gives little effect on the mineral assemblage compared to HTA samples. X-ray diffraction patterns of Suncor and Syncrude coke ash were analyzed qualitatively and quantitatively to characterize the mineral phases in the sample and their thermal transition behavior. In Suncor ash, kaolinite, illite, gypsum, anhydrite, microcline, anorthite, hematite, sillimanite and quartz were dominant phases in ash from the LTA temperature up to 700 °C, and mullite, cristobalite, hercynite, albite, anorthite, pseudobrookite and other iron–titanium oxides were dominant mineral phases from 700 to 1200 °C. In Syncrude ash, illite, anhydrite, quartz, anorthite, microcline, sillimanite and hematite were dominant up to 700 °C, and hercynite, anorthite, albite, pseudobrookite and other iron–titanium oxides were dominant up to 1200 °C. The higher quantities of Ca, K and Na, and the lower quantities of V, Fe and Ni in Syncrude ash resulted in higher amorphocity and the different mineral phases.

Minimal ecological management

Authors Ross, L.
Year of Publication: 2011

Abstract:
This report project background information and expands on what Ducks Unlimited Canada (DUC) considers its fundamental guiding principles for ensuring Minimum Ecological Management on its constructed wetland projects. While these principles were initially established for their constructed wetland projects, they now apply to almost all of DUC s habitat projects across Canada including upland and wetland restorations.

Minimal health impacts but detectable tissue residues after exposure of northern leopard frogs (Lithobates pipiens) to commercial naphthenic acids (PO)

Year of Publication: 2011

Abstract:
Naphthenic acids (NAs) have been implicated as one of the main causes of the toxicity related to oil sands process‐affected materials (OSPM). However, previous studies suggest that NAs may not be the toxic component of OSPM. This study investigated the toxicity of commercial (Refined Merichem) NAs to native amphibians (northern leopard frogs) concurrently exposed to saline conditions comparable to those of reclaimed wetlands on the oil sands. Frogs were kept in NAs solutions (0, 20, or 40 mg L‐1) for 28 days. These exposures resulted in proportional NAs concentrations in extracts of frog muscle tissue, estimated by GC‐MS analyses. Biological assays determined if the increasing exposure concentrations of NAs, and subsequently increased tissue NAs levels, caused a proportional compromise in the health of test animals. Investigations of innate immune function, thyroid hormones, and hepatic detoxification enzyme induction did not differ in response to increased tissue concentrations of NAs. Our results demonstrate that commercial NAs are absorbed and deposited in muscle tissue, and that NAs may play a small role, if any, in the toxicity of OSPM to frogs.

Miracle on the Athabasca

Authors
Year of Publication: 1965

Citation:

Misplaced generosity: Update 2012: Extraordinary profits in Alberta's oil and gas industry

Authors
Year of Publication: 2012

Abstract:
Recently released data on the tar sands industry reveals that things have returned to normal. Unfortunately for Albertans, "normal" is a royalty regime that ensures the vast majority of wealth goes to the private oil companies rather than the public, the owners of the bitumen. The diverging fortunes of the province and the oilpatch are clearly evident from the contrast between the government's ongoing revenue crisis, which has resulted in a $3 billion deficit, and the growing profits being reported by the oil industry. Suncor, Canada's largest oil and gas company, reported yearly profits of $4.3 billion, while Imperial Oil, which is 70% owned by U.S.-based ExxonMobil, made profits last fiscal year of $3.37 billion, the second largest in its record.

Mixing characteristics of the Athabasca River below Fort McMurray - Winter conditions

Authors Beltaos, S.
Year of Publication: 1979

Abstract:
This report presents the results of a comprehensive assessment of mixing characteristics of the Athabasca River below Fort McMurray under ice-covered flow conditions. A brief review of mixing processes in natural streams is followed by a description of two tracer tests conducted in February 1978 to provide the necessary field documentation of the Athabasca River. The results of these tests are analysed using recent theoretical models available in the literature. An average value for the transverse mixing coefficient is determined from the results of the first test which was a steady state test. This coefficient compares favourably with that found from a preliminary test in 1974 under similar flow conditions. The results of the second test, which involved central injection of a slug, are compared with a one dimensional model developed earlier by the author. This model is shown to give fair predictions beyond 20 km from the injection site. It is suggested that this limiting distance be increased to about 80 km when side injection of a slug is considered. To model the results of the slug test within the first 20 km from injection, a numerical algorithm is utilized together with the mixing coefficient found from the first test and shown to give fair predictions. The effects of bars and islands on applications of this algorithm appear to be of localized nature. It is suggested that such effects be ignored unless pertinent hydrometric data are available in considerable detail. Practical applications of the present findings are illustrated by working out two hypothetical examples. Finally, some recommendations are made for future research required to completely define the mixing characteristics of the Athabasca River and Delta system.

Modeling and analysis of actual evapotranspiration using data driven and wavelet techniques

Authors Izadifar, Z.
Year of Publication: 2010

Abstract:
Large-scale mining practices have disturbed many natural watersheds in northern Alberta, Canada. To restore disturbed landscapes and ecosystems’ functions, reconstruction strategies have been adopted with the aim of establishing sustainable reclaimed lands. The success of the reconstruction process depends on the design of reconstruction strategies, which can be optimized by improving the understanding of the controlling hydrological processes in the reconstructed watersheds. Evapotranspiration is one of the important components of the hydrological cycle; its estimation and analysis are crucial for better assessment of the reconstructed landscape hydrology, and for more efficient design. The complexity of the evapotranspiration process and its variability in time and space has imposed some limitations on previously developed evapotranspiration estimation models. The vast majority of the available models estimate the rate of potential evapotranspiration, which occurs under unlimited water supply condition. However, the rate of actual evapotranspiration (AET) depends on the available soil moisture, which makes its physical modeling more complicated than the potential evapotranspiration. The main objective of this study is to estimate and analyze the AET process in a reconstructed landscape. Data driven techniques can model the process without having a complete understanding of its physics. In this study, three data driven models; genetic programming (GP), artificial neural networks (ANNs), and multilinear regression (MLR), were developed and compared for estimating the hourly eddy covariance (EC)- measured AET using meteorological variables. The AET was modeled as a function of five meteorological variables: net radiation (Rn), ground temperature (Tg), air temperature (Ta), relative humidity (RH), and wind speed (Ws) in a reconstructed landscape located in northern Alberta, Canada. Several ANN models were evaluated using two training algorithms of Levenberg-Marquardt and Bayesian regularization. The GP technique was employed to generate mathematical equations correlating AET to the five meteorological variables. Furthermore, the available data were statistically analyzed to obtain MLR models and to identify the meteorological variables that have significant effect on the evapotranspiration process. The utility of the investigated data driven models was also compared with that of HYDRUS-1D model, which is a physically based model that makes use of conventional Penman-Monteith (PM) method for the prediction of AET. HYDRUS-1D model was examined for estimating AET using meteorological variables, leaf area index, and soil moisture information. Furthermore, Wavelet analysis (WA), as a multiresolution signal processing tool, was examined to improve the understanding of the available time series temporal variations, through identifying the significant cyclic features, and to explore the possible correlation between AET and the meteorological signals. WA was used with the purpose of input determination of AET models, a priori. The results of this study indicated that all three proposed data driven models were able to approximate the AET reasonably well; however, GP and MLR models had better generalization ability than the ANN model. GP models demonstrated that the complex process of hourly AET can be efficiently modeled as simple semi-linear functions of few meteorological variables. The results of HYDRUS-1D model exhibited that a physically based model, such as HYDRUS-1D, might perform on par or even inferior to the data driven models in terms of the overall prediction accuracy. The developed equation-based models; GP and MLR, revealed the larger contribution of net radiation and ground temperature, compared to other variables, to the estimation of AET. It was also found that the interaction effects of meteorological variables are important for the AET modeling. The results of wavelet analysis demonstrated the presence of both small-scale (2 to 8 hours) and larger-scale (e.g. diurnal) cyclic features in most of the investigated time series. Larger-scale cyclic features were found to be the dominant source of temporal variations in the AET and most of the meteorological variables. The results of cross wavelet analysis indicated that the cause and effect relationship between AET and the meteorological variables might vary based on the time-scale of variation under consideration. At small time-scales, significant linear correlations were observed between AET and Rn, RH, and Ws time series, while at larger time-scales significant linear correlations were observed between AET and Rn, RH, Tg, and Ta time series.

Modeling assessment of end pit lakes meromictic potential

Authors
Year of Publication: 2004

Abstract:
End Pit Lakes are proposed as a final remediation solution for oil sands reclamation and operational waters. The main objective of the CEMA RWG's End Pit Lake Sub-group is to establish design and management guidelines for these oil sands lakes. Golder Associates was commissioned to model the main factors controlling the occurrence of stratification.

Modeling soil acidification in the Athabasca oil sands region, Alberta, Canada

Year of Publication: 2009

Abstract:
Industrial activities have proliferated across Canada’s Athabasca Oil Sands Region in recent years, stimulating concerns over the impact of atmospheric sulfur dioxide (SO2) emissions on acid-sensitive terrain. Upland jack pine forests have been identified as possibly the most sensitive ecosystem in the region but despite high emissions of SO2, sulfur (S) deposition is relatively low across much of the region. The response of forest soils at 11 locations that exhibit low estimated weathering rates (<10 mmolc·m−2·yr−1) was simulated for the period 1900−2100 using a dynamic hydrogeochemical model assuming no change or doubling of S deposition. The model predicted minimal impact on soil base saturation (BS), but a decline in soil solution base cation (BC) to aluminum (Al) ratio (BC:Al). The regional effects-based emissions management framework uses modeled changes in these two parameters relative to site-specific chemical thresholds to trigger actions to reduce S emissions. Modeled changes in BS are insufficient to invoke a response. Under base case conditions, modeled BC:Al reaches the chemical threshold at two and three sites within 15 and 30 years, respectively. Under conditions of double S deposition, seven sites are simulated to reach the threshold within 30 years. Nonetheless, the chemical thresholds are stringent relative to critical chemical criteria used elsewhere and the impacts of acidic deposition in the region are anticipated to be limited.

Modeling the ecotoxicity of naphthenic acids

Year of Publication: 2010

Abstract:
Oil sand-derived process water is comprised of mixtures of many different toxic compounds. Recent modelling studies have been developed to assess oil sand ecotoxicity caused by naphthenic acids (NA). The hydrocarbon block method was used to described the ecotoxicity of NA mixtures using a database of physico-chemical properties for individual hydrocarbons. Chemical speciation and biota partitioning models are used to characterize the toxicity of ionizable compounds. An analysis of model predictions has suggested that high MW and compounds from the higher Z families contribute significantly to the ecotoxicity of oil sand-derived process water. However, the current modelling method overpredicts the toxicity of the highest residual fractions, which suggests that the bioavailability of the highest MW compounds is limited. Further model refinement is needed to evaluate NA compounds across a wide range of MW and Z families.

Modeling the energy demands and greenhouse gas emissions of the Canadian oil sands industry

Year of Publication: 2007

Abstract:
In this study, the energy requirements associated with producing synthetic crude oil (SCO) and bitumen from oil sands are modeled and quantified, on the basis of current commercially used production schemes. The production schemes were (a) mined bitumen, upgraded to SCO; (b) thermal bitumen, upgraded to SCO; and (c) thermal bitumen, diluted. Additionally, three distinct bitumen-upgrading methods were modeled and incorporated into schemes a and b. In addition to energy demands, the model computes the greenhouse gas (GHG) emissions associated with supplying the energy required to produce bitumen and SCO. This study comprises two distinct situations. The first is the base case in which all the energy is produced using current technology, in the year 2003. The second situation is a future production scenario, where energy demands are computed for SCO and bitumen production levels corresponding to the years 2012 and 2030. The results from the base case include the energy demands for producing thermal bitumen and mined bitumen, upgraded to SCO. These demands are expressed in terms of amounts of hot water, steam, power, hydrogen, diesel fuel, and process fuel for upgrading processes. The model output indicates that the majority of the GHG emissions (70−80%) result during bitumen upgrading. Additionally, it was found that steam, hydrogen, and power are the most GHG-intensive energy inputs to the process, accounting for 80% of the GHG emissions in the base case. CO2 accounts for 95% of the total GHG, while methane and nitrous oxide are responsible for the remaining GHG emissions of all the producers in the base case. The energy demands for production estimates in the years 2012 and 2030 are also presented. Of all energy commodities, steam demands for thermal bitumen extraction, as well as hydrogen demands for upgrading are poised to multiply roughly 6-fold by 2030, with respect to 2003 levels. The model results reveal that electricity and steam demands for upgrading and mining operations will roughly double by 2012 and increase by a factor of 2.4 between 2012 and 2030.

Modelling

Year of Publication: 1976

Modelling carbon isotopes in spruce trees reproduces air quality changes due to oil sands operations

Year of Publication: 2014

Abstract:
Direct monitoring of air quality does not cover more than the last three decades in most industrialized countries. For that reason studies using growth-ring carbon isotopes (δ13C) of several species of trees have recently investigated isotopic responses in the contexts of stationary and diffuse pollution in humid continental conditions. Here, the growth-ring δ13C series (1880–2009) of spruce trees living in sub-humid subarctic conditions were measured to assess if they represent indicators for air quality changes near oil sands (OS) developments initiated in northeastern Alberta in 1967. The measured δ13C pre-operation rings at two forest sites were analyzed along local climatic conditions to develop response-to-climate statistical models and predict the natural isotopic behaviour for the most recent part of the ring series. The measured trends and climate-modelled (natural) δ13C values strongly depart during the operation period, depicting anomalies which can be nicely reproduced by multiple regression models combining climate and a proxy for OS airborne emissions. This research allows envisioning the use of carbon dendroisotopic indicators to compensate for the lack of long-term air quality measurement, and monitor environmental conditions in the sub-humid terrestrial ecosystem exposed to emissions from oil sands operations which are predicted to increase in the future.

Modelling catchment response to acid deposition: A regional dual application of the MAGIC model to soils and lakes in the Athabasca oil sands region, Alberta

Year of Publication: 2010

Abstract:
The effects-based acid emissions management framework (EMF) for determining the need for emission control policies in the Athabasca Oil Sands Region, Canada is dependent on model simulations of future soil and surface water chemistry. An approach for regional application of the Model of Acidification of Groundwater in Catchments (MAGIC) was developed that addresses the differential sensitivity of forest soils and lakes. The approach used was a dual application wherein a plot-scale calibration to forest soils and a catchment-based calibration to lake chemistry were used to account for poorly understood hydrologic connections between uplands and lakes, key processes including sulphur (S) and nitrogen (N) retention as well as groundwater sources of base cations to the lakes. The regional application was carried out at 50 lake catchments currently monitored for response to acid deposition. Simulated forest soil chemistry (modelled at 28 catchments) exhibited small changes in base saturation under future conditions of elevated acid deposition, while in general molar BC:Al exhibited considerable change but remained well above critical chemical limits used to protect acid-sensitive forest soils. Similarly, simulations of charge balance acid neutralizing capacity (ANCCB) for the lakes suggested very small decreases since industrialization, and forecast projections under acid deposition double the current level suggested that only one lake will reach the critical threshold for ANCCB (75 μeq L–1) specified by the EMF. There is limited potential for acidification impacts at the study sites.

Modelling the circulation and sediment distribution in the Athabasca Delta area

Year of Publication: 1982

Abstract:
This project undertook an assessment of the potential for using satellite imagery to determine water quality parameters in the southwest end of Lake Athab8sca and to provide a mathematical model capable of simulating the circulation patterns in this area of the lake. A substantial amount of field data was collected for calibration purposes and served to ellucidate some of the hydraulic characteristics of the study area. The results indicated that water from the Athabasca River and its distributary channels could reach the north shore of the lake under conditions of moderately large inflow. It had been previously assumed that penetration of river water so far into the lake was unlikely. In addition, river water was found to extend up to at least 20 km northeast of the distributary channels. Water from the Embarras River and Fletcher Channel generally leaves the lake via the Chenal des Quatres Fourches while water from Big Point Channel generally discharges through the Riviere des Rochers. Correlation of LANDSAT imagery with contemporaneous water quality data yielded a high correlation between suspended sediment concentrations and band 6 digital response values. No other water quality parameters were correlated with the raw LANDSAT data. Principal component analysis of the satellite data indicated a high correlation between suspended sediment and the first principal component, which emphasized the infrared bands. In addition, conductivity was well correlated with the third principal component, which emphasized the difference between the visible bands. This result could prove beneficial in analysing satellite imagery since conductivity is a useful parameter for differentiating between lake and river water. A finite element model was developed which solves the vertically integrated momentum and continuity equations. Based on an implicit time stepping algorithm, the model was used to generate circulation patterns for an idealized representation of the study area.

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