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Oil Sands Environmental Management Bibliography

The Cumulative Environmental Management Association (CEMA)partnered with the Oil Sands Research and Information Network (OSRIN) to create the new Oil Sands Environmental Management Bibliography, which includes documents relevant to the environmental management of oil sands development in Alberta. The majority of the documents focus on the mineable oil sands in the Athabasca deposit, though some documents relate to in-situ developments. This bibliography was last updated in November 2014.

Hydraulic flood routing models of the Peace and Slave rivers, Hudson Hope to Great Slave Lake

Authors Hicks, F. E., & McKay K.
Year of Publication: 1996

Abstract:
Describes a hydraulic flood routing model developed to accurately model the open water river discharge on the Peace and Slave rivers. The model is capable of modelling the discharge at sites where no discharge data exist. The document includes description of the development of the database for the model, including the geometric database (channel distances, surface slopes, bed profiles, channel widths and resistances) and the hydrologic data. The appendix includes a user manual for the user-friendly microcomputer program that has been set up to run historical flows (1961-93) and to simulate naturalised flows on the Peace River (1969-91).

Hydraulic modelling of Peace-Athabasca Delta under modified and natural flow conditions

Authors Aitken, B., & Sapach R.
Year of Publication: 1994

Abstract:
Construction of the Bennett Dam in British Columbia altered natural fluctuations of downstream flows in the Peace River in Alberta, with major implications for the ecosystem of the Peace-Athabasca Delta. In later years, downstream weirs were constructed to restore the water level regime in the Delta. This report presents the results of a modelling exercise undertaken in an attempt to assess the effect of the weirs and the dam on the Delta water levels during 1985-90, at which time Lake Athabasca water levels were low and it was not clear whether the weirs were functioning properly or if the low water levels were caused by low flows coming from the upper Peace and Athabasca river basins. The methodology uses a one-dimensional hydrodynamic model, suitably modified and calibrated. The appendices include numerous plots of water levels indicating the effects of the weirs and dam on natural conditions.

Hydraulic performance of the seepage collection ditches at the Albian Sands Muskeg River Mine

Authors Yasuda, N.
Year of Publication: 2006

Abstract:
The tailings pond at the Muskeg River Mine is a large structure with a 11 km-long ring dyke that contains process affected water (PAW) and tailings sand. The dyke is made of permeable tailings sand and therefore it is equipped with seepage collection ditches that are designed to collect water from drains in the dyke but also to intercept seepage water not collected by the drains and transmit it to the seepage pond for recycling. The effectiveness of this seepage collection system was examined at the downgradient end of the tailings pond (Study Area) where near-surface permeable sand is present. <br /><br /> Piezometric level measurements were performed and water samples were collected from a network of 21 piezometers and drive points, and at several other critical locations. Concentrations of major chemical tracers of PAW such as naphthenic acids (NAs) show signs of migration of PAW in the permeable sand deposit, beyond the dyke. This interpretation is supported by stable O and H isotope analysis of water. The interpretation of the piezometric and chemical data revealed that the PAW has migrated past the Inner Ditch but not beyond the Outer Ditch. Elevated hydraulic heads beyond the Outer Ditch prevented further migration. Groundwater locally converges and discharges as surface water in the wet area between the two ditches. Thus, the collection ditch system is currently working effectively to contain PAW. <br /><br /> Numerical modeling of the Study Area was able to reasonably recreate the observed hydraulic conditions. Based on these simulations, it is possible that PAW may be migrating through a permeable layer of sand under the bottom of the dyke and pond, and eventually discharging into the wet area between the ditches. The estimated amount of PAW seepage discharged into the wet area is small compared to the total dyke drainage collected by the ditches. <br /><br /> These conditions described above, however, may change with the progress of the current dyke expansion work. The wet area between the ditches will be buried and the local hydraulic condition is expected to alter. This may reverse the hydraulic gradient across the Outer Ditch and perhaps will facilitate migration of PAW beyond the Outer Ditch. It is recommended that the following key chemical parameters be used in future groundwater quality monitoring efforts to track PAW migration at the Muskeg River Mine: Na<sup>+</sup> Cl<sup>-</sup> , SO<sub>4</sub><sup>2-</sup> , and Ca<sup>2+</sup> ions, stable isotopes of hydrogen and oxygen, and Naphthenic acids (NAs. )

Hydro-Climate Model Selection and Application on the Athabasca and Beaver River Basins

Authors
Year of Publication: 2009

Abstract:
As part of a regionally specific initiative for the Lower Athabasca Regional Plan, Alberta Environment has identified the need for a hydrologic model to assist it in assessing the effects of climate change on water yield in the lower Althabasca Regional Plan Area, and in the Athabasca River Basin and the Beaver River Basin, in particular. This document can be downloaded from our FTP website - please follow the link on the right. Because of its size, it has been broken down into the Report itself, Figures and Tables, and Appendicies.

Hydrocarbon recovery from waste streams of oil sands processing

Authors Thomas, T.
Year of Publication: 2011

Abstract:
Bitumen recovery by the water-based extraction process produces waste streams known as tailings. When discharged into the tailing ponds, the coarse solids in the tailings stream settle out quickly, while the fine solids accumulate over years of settling to a solids content of 30-35% by weight. The formed fluid fine solids sludge, known as mature fine tailings (MFT), traps 1-3% by weight hydrocarbons within its stable slurry structure. The remediation of these mature fine tailings is one of the major challenges facing the oil sands industry. This study was intended to investigate the recovery of residual hydrocarbons in the MFT by froth flotation process. Using a laboratory Denver flotation cell operated in a batch mode, the effect of MFT dilution ratio by process water or tap water, the flotation hydrodynamics and aeration rate on hydrocarbon recovery kinetics was studied. It was found that at 1:2 dilution by weight of the MFT with process water, increasing aeration rate has a more favourable effect on recovering more than 85% of the hydrocarbons from the MFT. The hydrocarbon-rich froth produced was treated by naphtha and was found to produce a hydrocarbon product similar to diluted bitumen obtained in bitumen extraction process, suitable for upgrading. Similar approach was applied to the hydrocarbon-rich tailings from the Tailings Solvent Recovery Unit of paraffinic froth treatment. Satisfactory recovery of hydrocarbons from the MFT was obtained using a flotation column operated in a continuous mode, confirmed the results obtained from the batch tests. The tailings produced from the continuous flotation experiments were treated with polymer flocculants such as Magnafloc-1011 and Al-PAM to study the effect of hydrocarbon recovery on the remediation of the MFT. The results from initial tests showed that both flocculants were not as effective on flocculating MFT solids following the recovery of hydrocarbons by froth flotation.

Hydrocarbons in natural oil sands soils: Field survey

Authors
Year of Publication: 2006

Abstract:
This report describes the result of a field survey to map the extent and characteristics of naturally occuring hydrocarbons (tar, bitumen, oil) enriched sand materials in soils of the oil sands region. The survey focused on townships where oil and sand presence in soils was previously identified based on a literature review (Leskiw 2005). Results are presented on base maps showing terrain, dominant soils and ecosites derived from mapping for the study area as used in recent environmental impact studies.

Hydrocarbons in natural soils: Literature review

Authors Leskiw, L. A.
Year of Publication: 2005

Abstract:
This report contains a summary of a literature review on hydrocarbons in natural soils. Regional information, primarily from the Soils Inventory of the Alberta Oil Sands Environmental Research Program Study Area (AOSERP Report 122) (Alberta Environment 1982), was used as a base to provide an overview of bedrock geology, surficial materials, physiographic units, and soils, highlighting areas with reported tar sand in the soils. Results from more recent field studies supplement this original survey to show the regional distribution of tar sand in soils. Field sheets and summaries of inspection sites for Baseline Soil Surveys of submitted Environmental Impact Assessments were reviewed to identify points where tar sand was encountered in soils. In most cases, tar sand was mentioned but very few samples were taken for hydrocarbon analysis. A total of more than 15 000 inspection sites were reviewed from existing and planned developments, as shown in Figure 1. Data from the Soil and Vegetation Plots was also added to the review. An accompanying spreadsheet tabulates all inspection sites, GPS coordinates, soil series, and parent materials along with brief comments at sites where tar sand was mentioned. It was evident that in some cases field sheets noted tar sand in the profile, but the comments did not necessarily appear in the published inspection site summaries. Thus, there may be omissions of observed tar sand. Nevertheless, the broad picture shows widespread distribution of shallow tar sand in the oil sands region.

Hydrochemistry of Phanerozoic Strata northeast Alberta

Authors Hitchon, B.
Year of Publication: 1991

Abstract:
The Northeast Alberta study area is defined as 55� to 58�N, and 110� to 114� W. A total of 2933 formation water analyses from the area were entered into the Alberta Geological Survey Well Data Base, verified, and subjected to a variety of electronic, manual-electronic and manual culling to leave a final data base of 525 analyses on which this study was based. Salinity ranges from freshwater to 325,000 mg/l, and there are corresponding maximum contents of Cl (200,000 mg/l), Ca (40,000 mg/l) and Mg (8000 mg/l). Nine maps illustrate the distribution of salinity, which is essentially depth (temperature) related except where there is incursion of fresher waters from overlying aquifers. Sulfate is high (500-5500 mg/l) in aquifers in which anhydrite is present (Elk Point hydrostratigraphic unit -- Prairie Formation; Beaverhill Lake aquifer -- Fort Vermilion Formation; and Grosmont aquifer -- Hondo Formation). Formation waters in the Elk Point hydrostratigraphic unit from near the updip solution edge of the Prairie aquiclude (halite) are similar to those of saline springs in the valley of the Athabasca River, which have been shown to originate from solution of evaporites by meteoric water. Based on the composition of their formation waters the aquifers can be combined into groups separated by aquitards, as follows: Viking aquifer (weak Joli Fou aquitard); Grand Rapids aquifer (strong, regional Clearwater aquitard); Clearwater, Wabiskaw and McMurray aquifers; Wabamun and Winterburn aquifers (weak Upper Ireton aquitard); Grosmont aquifer (strong Lower Ireton aquitard); Beaverhill Lake aquifer (significant, regional Prairie aquiclude); Elk Point hydrostratigraphic unit (mainly Keg River aquifer); Precambrian aquiclude. In summary, the formation waters of the Northeast Alberta area are an extension of those in the adjacent Peace River Arch area, exhibit similar characteristics, and have similar origins.

Hydrodesulfurisation of Athabasca fluid coke

Authors Saha, C.
Year of Publication: 1992

Abstract:
Oil sands coke is a secondary product of bitumen upgrading via coking. The high sulfur content makes Athabasca fluid coke unusable as a fuel. The removal of sulfur from coke by reaction with hydrogen at high temperatures was investigated. The effects of particle size, temperature and gas flow rates on fixed bed hydrodesulfurization of Syncrude fluid coke were studied. Desulfurisation was found to be affected by the above parameters but showed maximum sensitivity to temperature. The initial global reaction rate decreased about twelve times over 90 minutes. Experimental data showed a good fit with the predictions of the shrinking core model. The process is controlled initially by the gas film and chemical reaction resistances. With time, the diffusion of hydrogen through the increasing ash layer becomes rate controlling. At temperatures ranging from 973 to 998 K the process is chemical reaction controlled while at higher temperatures it is mass transfer controlled.

Hydrogeologic characterization of a newly constructed saline-sodic clay overburden hill

Authors Chapman, D. E.
Year of Publication: 2008

Abstract:
Syncrude Canada Ltd (Syncrude) Mildred Lake operation is the largest producer of crude oil from oil sands mining in Canada. A saline-sodic clay-shale overburden known as the Clearwater Formation (Kc) must be removed in order to access the oil-bearing McMurray Formation (Km). The potential concerns associated with the reclamation of overburden structures include shale weathering and salt release and migration, resulting in salinization of groundwater, surface water, and reclamation soil covers. South Bison Hill (SBH) is one example of a Kc overburden structure located at the Syncrude Mildred Lake Operation. The general objective of this study is to develop a preliminary conceptual/interpretative model of the hydrogeology of the newly reclaimed SBH at the Syncrude mine site. A number of tasks were undertaken to meet this general objective. The first, and most important aspect of this study was to develop a geological model of SBH including pile geometry and depositional history of the hill. Secondly, to gain an understanding of the field conditions, a program was carried out over 2002 and 2003 to obtain pile physical characteristics. The geological model revealed that there are four main geological sections of SBH of different materials using different construction methods. The field data were used to verify the geological model, which illustrated the differences in hydraulic conductivities and geochemical signatures between the different sections. All information was used to develop a simple steady-state numerical seepage model of SBH to be used as a tool to investigate the response of the water levels of SBH to variations in the model parameters. The model illustrated that groundwater flow is largely controlled by a more permeable section on the south side of SBH and an unstructured Kc fill at the base of the pile. A sensitivity analysis was conducted on the model changing the flux into the pile, the permeability of the materials, and most importantly the head value of the tailings facility located on the north side both showing to be influential on the elevation of the water table through SBH.

Hydrogeological investigation of Muskeg River basin, Alberta

Authors Schwartz, F. W.
Year of Publication: 1980

Abstract:
Detailed studies of groundwater-surface water systems in Hartley Creek basin show the creek to be at baseflow for only a few months in the winter when other contributions to streamflow are negligible. Following spring snowmelt, drainage of muskeg is the major contributor to streamflow along with groundwater inflow. Similar patterns of streamflow generation were observed for Firebag, Steepbank, and Muskeg rivers as well as Thickwood Creek. Quantitative hydrograph separations for these basins show that the main differences result from variable amounts of inflow from muskeg during winter. Muskeg River like Hartley Creek is close to baseflow in winter. However, in Firebag River and Thickwood Creek, drainage from muskeg may comprise as much as 40 to 50% of the streamflow in winter. Streamflow in all basins will be influenced by the disturbance of muskeg. For the particular case where muskeg is removed and replaced by mineral soils, stream discharge will tend to decrease during summer and to increase during spring runoff and stormflow periods. In cases where the local disturbance of muskeg is considerable, marked variation in streamwater chemistry can be anticipated.

Hydrogeology of the post-Devonian sedimentary succession at the AOSTRA Underground Test Facility

Year of Publication: 1996

Abstract:
This report presents the geology and hydrogeology of the post-Devonian sedimentary strata at the Underground Test Facility (UTF) near Fort McMurray in northeastern Alberta where bitumen is extracted from the McMurray oil sands using the Steam Assisted Gravity drainage (SAGD) process. The report is a result of a collaborative agreement between Environment Canada and the Alberta Research Council to study the possibility of shallow groundwater contamination at the UTF site by fluids escaping the production zone and migrating upwards. The Oil Sands and Research Division of the Alberta Department of Energy (formerly the Alberta Oil Sands Technology and Research Authority) supported the study by providing access to relevant data.

Hydrometeorological conditions controlling ice-jam floods, Peace River near the Peace-Athabasca Delta

Year of Publication: 1996

Abstract:
This study stemmed from the concerns raised regarding the long term trying trends affecting the Peace Athabasca Delta (PAD), one of the world's largest freshwater deltas. A common perception during the 1970's and 1980's was that lower flows on the Peace River due to regulation by the W.A.C. Bennett Dam, minimized the probability of large open water flood events capable of inundating the perched basins of the PAD adjacent to the Peace River. Local traditional knowledge and other anecdotal information suggested that ice jams also played a role in some flood events. Analysis of hydrometric data in conjunction with various historical and local-knowledge sources confirms that open-water floods have been ineffective in producing high-elevation floods along the Peace River adjacent to the Peace-Athabasca Delta. Even the historically high flow event of 1990 did not produce a flood of sufficient magnitude to flood high-elevation portions of the delta. Over the period of hydrometric record, backwater produced during river-ice breakup has exceeded that of the 1990 open-water event on several occasions. It was breakup backwater, in 1974, that resulted in the last major flooding of the elevated perched basin within the PAD. In the lower portions of the Peace River, flow regulation seems to have produced minor changes in factors, such as ice thickness and strength, that could significantly affect the severity of breakupandrelatedice-jamflooding. Temporalanalysisofthesefactors,however,alsodetected a weak climate signal suggesting that since approximately the mid-1970's the period of ice cover may have become slightly warmer and the pre-breakup melt period may have become more intense and/or more protracted. A common perception was that reduced flows due to regulation were responsible for the decline in severe ice jams. Flow contributions from the point of regulation, however, are higher, on average, at the time of breakup near the PAD in the post-regulation period than prior to regulation. The major ice-jam floods that occurred in the 1960's prior to regulation and in the early 1970's after regulation have been associated with large runoff events from downstream tributaries especially the Smoky River. These large tributary flow events also appear to be correlated with large spring snowpacks and associated snowmelt runoff. A preliminary evaluation of temporal trends in the size of the snowpack on the Smoky River suggests that there has been a shift in the mid-1970's to values lower than the long-term average. A similar trend in snowpack accumulation has been identified in British Columbia. The major effect of regulation on the occurrence of breakup ice jamming near the Peace- Athabasca Delta is related to higher winter flows and increased freeze-up elevations. In general, the higher a freeze-up cover, the greater the flows it can pass without breaking. Two runoff sources combine to generate spring flows that can exceed the freeze-up level:: the upstream flow from above the point of regulation and the downstream tributary flow. Under regulated conditions, a major increase in upstream flows (above the point of regulation) is unlikely at the time of breakup near the Peace River Delta due to the operational transition to lower summer releases. Furthermore, if the amount of regulated flow at the time of breakup is declining, tributary flow will have to account for this "loss" to the main-stem discharge, before having an affect on the ice cover. Under the current regulated regime, production of severe breakups has become more dependent on tributary inflow, particularly from the Smoky River. Large spring runoff from the tributaries have been effective since regulation in producing large breakup floods (e.g., 1972 and 1974) but the apparent decline in spring snowpacks has reduced their subsequent effectiveness. Thus the absence of a large-order event since 1974 seems to be related to a combined effect of flow regulation and the vagaries of climate.

Hydrotechnical research in the Alberta oil sands

Authors Sneddon, D. T.
Year of Publication: 1983

Abstract:
Hydrotechnical research in the Alberta Oil Sands has been oriented toward establishment of baseline (i.e. pre-development) environmental conditions and identification of contaminant transport mechanisms. Monitoring networks for both groundwaters and surface waters are in place and both water yield and quality are being observed. Plans are being made for research into groundwater/surface water interaction and into the geomechanical consequences of insitu extraction of bitumen using high pressure, high temperature steam injection techniques.

Hypogenic karst beneath the Athabasca oil sands - controls on aquifers and aquitards

Year of Publication: 2014

Abstract:
The Athabasca Oil Sands are located in northeast Alberta, Canada and contain an estimated 168 billion barrels of recoverable bitumen (Alberta Energy) that are developed through in-situ and mining operations. The bitumen-bearing reservoirs consist of a stacked sequence of Cretaceous-aged fluvial sediments that were deposited directly above subcropping middle and early upper Devonian limestones, dolostones, calcareous shales and evaporties. Regionally, dissolution of the middle Devonian evaporites was responsible for a dip reversal within the Devonian that created the Athabasca Anticline (Carrigy, 1959; Norris, 1963). It has been suggested that this structure was the primary trap for the hydrocarbon accumulation prior to extensive biodegradation (Ranger, 1994). Locally varying surface karst, combined with dissolution has resulted in complex structuring of the Devonian unconformity and both overlying and underlying stratigraphic units. Local collapse within the Devonian as a result of dissolution has been attributed to the development of sinkholes and release of water to surface from Devonian aquifers in active oil sands mining operations (Mahood et al, 2012). The distribution of aquifers and aquitards within the Devonian has important implications for the ongoing development of the Athabasca Oil Sands. Devonian aquifers provide an opportunity for in-situ projects, which require both a reliable source of non-potable water for steam generation and a suitable disposal zone. Conversely, Devonian aquifers pose a significant risk to oil sands mining operations, where influx of non-potable water into the mine poses safety, environmental and economic risks to mining operations. Understanding the distribution of aquifers and the distribution and integrity of aquitards within the Devonian is therefore a fundamental requirement for successful oil sands operations. The adjacent in-situ and mining operations have almost opposite business drivers. This paper presents our current understanding of hypogenic karst beneath the Athabasca Oil Sands and raises some important questions about where the fluids go.

Hypoxia affects root sodium and chloride concentrations and alters water conductance in salt-treated jack pine (Pinus banksiana) seedlings

Year of Publication: 2003

Abstract:
The effects of NaCl were studied in 6-month-old jack pine (Pinus banksiana Lamb.) seedlings growing in solution culture under hypoxic (approximately 2 mg lу O2) and well-aerated (approximately 8 mg lу O2) conditions. The results showed that hypoxia led to further reduction of stomatal conductance (gs) in plants treated with 45 mM NaCl. This effect was likely due to a reduction in root hydraulic conductance by both stresses. When applied individually or together, neither 45 mM NaCl nor hypoxia affected cell membrane integrity of needles as measured by tissue electrolyte leakage. Hypoxia did not alter shoot Na+ and Clm concentrations in NaCl-treated plants. However, root Na+ concentrations were lower in NaCl-treated hypoxic plants, suggesting that hypoxia affected the ability of roots to store Na+. Hypoxia also induced root electrolyte leakage from NaCl-treated and control plants. The higher root Clm concentrations compared with Na+ and the positive correlation between root Clm concentrations and electrolyte leakage suggest that Clm played a major role in salt injury observed in jack pine seedlings. Roots of well-aerated plants treated for 1 week with NaCl contained almost two-fold higher concentration of total non-structural carbohydrates compared with plants from other experimental treatments and these concentrations decreased in subsequent weeks. We suggest that under prolonged hypoxic conditions, roots lose the ability to prevent Clm uptake resulting in the increase in root Clm concentration, which has damaging effects on root cell membranes.

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