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Oil Sands Environmental Management Bibliography

The Cumulative Environmental Management Association (CEMA)partnered with the Oil Sands Research and Information Network (OSRIN) to create the new Oil Sands Environmental Management Bibliography, which includes documents relevant to the environmental management of oil sands development in Alberta. The majority of the documents focus on the mineable oil sands in the Athabasca deposit, though some documents relate to in-situ developments. This bibliography was last updated in November 2014.

RRTAC future research needs project Summary

Authors Smith, J. A.
Year of Publication: 1989

Abstract:
Concord Scientific Corporation was contracted to design a questionnaire program to determine the reclamation research needs of organizations/industries in Alberta that are involved with industrial disturbances. The company was also responsible for analyzing the questionnaire results and prioritizirg the research needs. This report is a Summary of the work, and is a condensed version of the final project report prepared by Judith Smith, Concord Scientific Corporation, for the Reclamation Research Technical Advisory Committee (RRTAC). The results of this study will be used by RRTAC to assist in establishing the direction to be taken in furthering government reclamation research over the next several years.

Salinity and solvent effects on the characterization of naphthenic acids from Athabasca oil sands using electrospray ionization

Year of Publication: 2010

Abstract:
This study investigated the salinity and solvent effects on the characterization of naphthenic acids (NA) in oil sands. The mass spectra of NA were obtained using an electrospray ionization method combined with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The study showed that while monocarboxylic compounds (CnH2n+zO2) in the z=-4, -6, and -12 of the 2,3 and 6-ring NA in the carbon number range of 13 to 19 were prevalent in the dichloromethane and acetonitrile co-solvent systems, the addition of salt resulted in a reduction of the observed species, the complete elimination of dicarboxylic acids, and an 80 per cent reduction in O3 species with similar carbon number range and z values. The dicarboxylic acids were also less toxic than monocarboxylic acids. Results of the study will be used to refine methods of remediating oil sands and process water contaminated soils.

Salinity interactions with boron root hypoxia and naphthenic acids in jack pine (Pinus banksiana Lamb.) seedlings

Authors Apostol, K. G.
Year of Publication: 2003

Abstract:
Open-pit mining of oil sands in north-eastern Alberta produces large volume of saline tailings. Aside from tailings being saline, they have high levels of boron (B), naphthenates and low levels of oxygen. These stresses can further exacerbate toxic effects of salt on plants and, consequently, affect the successful revegetation of the oil sands mining areas. The general objective of the present study was to understand the mechanisms of salinity interactions with other stress factors namely, B, root hypoxia and naphthenic acids (NAs). To address the objective, jack pine (Pinus banksiana ) seedlings were grown under controlled environment conditions and subjected to a combination of stresses, with salinity as a common stress factor. Results of the present work demonstrated the sensitivity of jack pine to salts and its susceptibility to salts was further increased by the presence of high concentrations of B, NAs and low levels of oxygen. Salinity altered jack pine responses to B. When present together with salts, B decreased survival and induced injury to plants. Among the distinct responses of jack pine to combined stresses were reduced root hydraulic conductance and stomatal conductance, which could alter root to shoot salt transport. The reduction in root water uptake observed in plants treated with NAs + NaCl explain the reduced accumulation of Na + and Cl- in the shoots. In another experiment, I observed that under hypoxic conditions, roots lost the ability to restrict Cl- uptake and the increase in Cl - concentrations was correlated with root electrolyte leakage suggesting that Cl- was partly responsible for membrane leakiness in the roots. Similar response was also observed in plants exposed to B + NaCl treatments, which showed that the Cl- -induced membrane injury was partly responsible for Na+ and B toxicity. The implication of this research for the revegetation of the oil sands following mining operations is discussed.

Salinization of soil over saline-sodic overburden from the oil sands in Alberta

Year of Publication: 2010

Abstract:
Saline-sodic mine overburden (also referred to as spoil) removed to access the oil sands in the Athabasca region of Alberta is used as backfill in open pits and is also placed in large upland structures. These deposits are reclaimed with a soil cover to support re-vegetation. The chemistry within reconstructed soil profiles over saline-sodic overburden was investigated to determine the nature and spatial distribution of salts in the soils. Four reclamation treatments were compared: three layered covers (35, 50 and 100 cm thick) and one non-layered cover (100 cm thick). Salts have accumulated in the cover soils 15 to 20 cm above the overburden, raising the electrical conductivity in the lower part of the soil to between 4.5 and 6.0 dS m 1, which is beyond the acceptable value for vegetation growth. Salt redistribution was not related to slope position and the pattern of salt ingress suggests that diffusion has been the main mechanism driving salt migration into the soils during the initial 4-yr period following placement. Cover thickness did not affect the extent of salt migration, but the overall quality of the thinner covers (35 and 50 cm) for vegetation growth was compromised by the increased salinity levels.

Salt movement in disturbed soils

Year of Publication: 1993

Abstract:
This literature review compiles information on salt movement in disturbed soils, particularly in soils that had been disturbed by pipeline construction. The review had two main objectives: to assess climatic and soil conditions under which salts will move out of the root zone in a disturbed soil and to determine the rate at which salts will move in disturbed soils. A literature base was established using computer database and library searches, and a number of studies were reviewed. Many of them, dealing specifically with salt movement over time in disturbed soils under climate and soil conditions similar to those found in Alberta, are summarized in tabular form. Data found in the literature tended to be sparse and incomplete, making it difficult to draw firm conclusions about rates of salt movement and conditions under which movement takes place. In the Brown Soil Zone, 5 years may be sufficient time for sodium adsorption ratio (SAR) and electrical conductivity (BC) levels, elevated during construction, to return to preconstruction conditions in coarse to moderately coarse textured soils. In medium to moderately fine textured soils, 10 to 26 years may be required to return soil salt content to pre-construction conditions. In the Dark Brown Soil Zone, 5 years appears to be marginal for a return to preconstruction conditions, being sufficient time in some cases, but not in others. Data in the Black Soil Zone were very limited, and results inconsistent. Studies from the U.S. were generally the result of research on mine reclamation. Most reported decreases in salts over relatively short periods of time, but the magnitude of the decrease varied greatly from study to study.

Salting-out effects on the characterization of naphthenic acids from Athabasca oil sands using electrospray ionization

Year of Publication: 2011

Abstract:
There is growing interest in the mass spectrometric characterization of oil sands acids present in natural waters and contaminated soils. This interest stems from efforts to isolate the principal toxic components of oil sands acid extractable organics in aquatic environment. Salting-out effects are demonstrated for nanospray ionization mass spectra of Athabasca oil sands acid extractable organics (naphthenic acids), using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. The differences in spectra obtained for the sodium naphthenates in dichloromethane/acetonitrile cosolvents compared to spectra obtained in the absence of saturated sodium chloride salts, are used here as a surrogate to indicate the more bioavailable or toxic components in natural waters. Whereas, monocarboxylic compounds (C(n)H(2n+Z)O(2)) were prevalent in the Z =-4, -6, and -12 (2, 3 and 6-ring naphthenic acids respectively) family in the carbon number range of 13 to 19 in the dichloromethane/acetonitrile cosolvent systems, salting-out effects resulted in a general enhancement of Z =-4 species, relative to others. Likewise, the shift in relative intensities of species containing O(1), O(3), O(4), O(2)S and O(3)S was dramatic for systems with and without saturated salts present. The O(4) and O(3)S species for example, were prevalent in the dichloromethane/acetonitrile cosolvent but were non-detected in the presence of saturated salts. Interactions of oil sands acids with salts are expected to occur in oil sands processed waters and natural saline waters. As evident by the distribution of species observed, salting-out effects will play a major role in limiting the bioavailability of oil sands acids in aquatic systems.

Sampling of formation waters in the Athabasca oil sands (in situ) area Alberta 1999-2001 - A compilation of protocols and methods

Authors Lemay, T. G.
Year of Publication: 2002

Abstract:
Between 1999 and 2001, the Alberta Geological Survey (AGS) completed a water-sampling program in northeastern Alberta. Water samples were collected from gas wells completed in the Lower Cretaceous Viking Formation, Colony Member, Grand Rapids Formation, Clearwater Formation, Wabiskaw Member and McMurray Formation. Samples were also collected from wells completed in the Upper Devonian Nisku and Grosmont formations. The results will be used to establish a baseline hydrogeochemical data set for these formations within the Alberta Energy and Utilities Board (EUB)-designated Athabasca Oil Sands (in situ) Area. The sampling protocols documented in this Geo-Note are the result of a subsequent literature review and of personal communication with a number of research scientists involved in formation-water sampling in the oil and gas industry. The protocols and methods include sections on: 1) site preparation and setup; 2) sampling for major, minor and trace elements, isotopes of O, H, C, B, S and Sr, organic acids, radionuclides, silica, C1, Br and I; 3) quality control; and 4) site cleanup and equipment decontamination.

Sand and soil: Ecological management and the framing of Mildred Lake

Authors Ritts, M. J.
Year of Publication: 2010

Abstract:
This paper explores representations of nature that emerge through the ecological management of Mildred Lake, Syncrude’s Alberta-based oil sands extraction facility. Examining the ways Mildred Lake’s ecology has been re-presented by site eco-management teams, I argue that technologically produced visions help reproduce the regime of power infusing a state-sanctioned scientific practice of eco- management. ‘Using governmentality theory, Chapter 1 contextualizes activities at Mildred Lake: I show how the Alberta government, tethering the growth of the oil sands to technological innovation, submits eco-management questions to a capital-driven state-developmental framework. Chapter 2 examines how state-sanctioned science is discursively performed through eco-management acts. Chapter 3 uses a case study approach to consider three Mildred Lake eco-management projects: Beaver Creek, the Tailings Pond, and reclamation. While Mildred Lake’s eco-management practices cannot withstand critical scrutiny, they reveal the culturally and ecologically significant transformations of nature required to sustain authority amid the destructive effects of bitumen extraction.

SAP based rapid dewatering of oil sands mature fine tailings

Authors Farkish, A.
Year of Publication: 2013

Abstract:
Mature fine tailings (MFT), as a mixture of residual bitumen, sand, silt, fine clay particles and water, are a byproduct of oil sands extraction. The large volume, and poor consolidation and water release ability of MFT have been causing significant economic and environmental concerns. Therefore, several studies have been implemented on finding innovative dewatering/disposal techniques. As a result, different methods have been introduced and tested at a laboratory or a field scale, yet very few of these are commercially used in the oil sands industries. Despite the extensive research, an optimal solution has not been found due to the lack of technical or economic feasibility. In the present study, a novel approach that consists of the rapid dewatering of MFT by using a super absorbent polymer (SAP) to produce dense MFT is proposed. A comprehensive laboratory investigation on the geotechnical characteristics and behavior before and after treatment of MFT is conducted. The effects of SAP based dewatering and freeze/thaw cycles on the undrained shear strength of dewatered MFT by using a vane shear apparatus are studied. Furthermore, the ability of recycled SAP to dewater and densify MFT is assessed. Finally, this study provides the results of consolidation and hydraulic conductivity testing to evaluate the void ratio versus effective stress and hydraulic conductivity of MFT. The effects on the behavior and characteristics of MFT after amendment with usage of recycled SAP are also investigated. The results indicate that SAP has the ability to significantly dewater, densify and increase the undrained shear strength of MFT. Furthermore, when subjected to freeze/thaw cycles, the MFT dewatered with SAP shows an additional increase in strength and solid content. It is also found to be possible to regenerate the polymer (still within sachets) through light thermal drying, and the regenerated SAP can still significantly dewater and thus increase the shear strength and solid content of the MFT. In addition, the obtained high solid content affects and improves the compressibility of the material, thus resulting in low initial void ratios. On the other hand, low hydraulic permeability that is derived from low initial void ratios and consolidation is improved by the freeze/thaw process due to the interconnected voids created during the freezing process.

Satellite remote sensing in assessing the environmental impact of large-scale surface mining operations

Authors Latifovic, R.
Year of Publication: 2006

Abstract:
This dissertation examines the capability of advanced remote sensing as a technique for investigating the cumulative impacts of large-scale open pit mining and processing operations. Long-term satellite measurements at medium (1km) and fine (30m) spatial resolutions are employed for assessing land cover and land use change resulting from mining development. Particular emphasis is placed on extracting information from remote sensing measurements needed for an effective assessment approach. The developed methods were used for investigating the environmental impact of oil sand mining located north of Fort McMurray, Alberta, in the Athabasca Oil Sands region.The outputs of the research contribute to the: (1) advance satellite data radiometric and geometric corrections, (2) methods for extracting geophysical parameters required for environmental monitoring and forecasting, and (3) use of remote sensing in assessing surface mining impacts on vegetation. This dissertation is organized into eight chapters. Chapter 1 provides relevant background information, a short research overview and identifies gaps and objectives. Chapter 2 examines the role, presents the general terminology and concepts used in environmental assessment studies. Chapter 3 focuses on environmental impacts associated with surface mining. It is structured according to the development activities associated with the mine lifecycle. Each activity is elaborated from the environmental aspect on which it may have an impact. Satellite images are used to illustrate examples of the impacts and to demonstrate the capability of remote sensing to detect different aspects of environmental degradation. Chapter 4 evaluates the potential links between remote sensing and quantitative impact assessment methods. It evaluates the information extraction procedures, change detection and other remote sensing techniques that can be used in quantitative impact assessment studies. Chapter 5 captures the range of specialized knowledge required for processing remote sensing data before they can be used in an environmental impact assessment study. It is focused on evaluating and understanding sources of noise present in satellite measurements and on data quality improvement throughout appropriate systematic corrections. Chapter 5 also presents a historical archive of radiometrically consistent satellite data generated for studying the environmental consequences of mining development in the Athabasca Oil Sands region. Chapter 6 and 7 present an innovative methodology for remote sensing based quantitative impact assessment, demonstrate and evaluate its use in a case study carried out on the Athabasca Oil Sands region for the period 1990-2002. Chapter 8 provides concluding remarks and the recommendations for future research.

Scoping exercise for indigenous ecological classification of wetlands in the Athabasca oil sands region

Year of Publication: 2008

Abstract:
This report describes the outcomes of the Scoping Study and presents a proposed research approach for the phase two Pilot Study. The goal of the second phase (Pilot Study) is to produce a set of community-identified wetland values that will contribute to the development of an indigenous ecological wetlands classification at a regional scale. This will be achieved through a field research programme working with the elders of a single community. The Pilot Study will also be used to test and refine the research approach identified in the Scoping Study (and described in this report) so that this approach can be more readily adopted in other areas.

Screening level review and assessment of metrics for the assessment and management of ozone effects on vegetation

Authors
Year of Publication: 2006

Abstract:
This document provides a review of metrics and indices that have been developed to evaluate ozone concentrations in ambient air in terms of potential impacts to vegetation. In current scientific and regulatory terms, each metric or index is used in the establishment of "critical levels," which are numerical expressions of ozone exposure at or above which a negative efect on plant growth is expected, based on current knowledge. Critical levels are similar in philosophy to the critical loads used to express the amount of acidic deposition above which negative effects are expected (again, based on current knowledge). It is not within the scope of this review to discuss or justify the scientific basis behind any of the metrics. More specifically, the scientific merit of any dataset used in the derivation o f the metrics discussed in this report is not discussed. The development and justification of the metrics have been presented in numerous reports, of which US EPA [7] and UNECE Convention on Long-range Transboundary Air Pollution [6] documents are particularly substantive. Indices describing vegetation effects have been established for plant groups, namely agricultural crops, horticultural crops, semi-natural vegetation, and forests. Within each group, a subset of species has been evaluated for their responses to ozone, and it is on the basis of these responses that indices and their respective critical levels have been derived. From the perspective of the NSMWG and the Ozone Management Framework, the data and metrics developed from them that relate to tree growth are the most relevant, given the boreal forest setting in the CEMA management area. Hence, metrics applicable to forest environments or forest trees are emphasized in this review. The main conclusions derived in 1996 on the basis of the National Crop Loss Assessment Network (NCLAN) studies, and reaffirmed by the US EPA [7] were: 1. Ozone effects in plants are cumulative; 2. Higher ozone concentrations are more important than lower concentrations in causing a plant response; 3. Plant sensitivity varies with time of day and developmental stage; and 4. Exposure indices that accumulate hourly ozone concentrations and preferentially weight higher concentrations better predict (statistically) plant responses than do indices based on average and peak concentrations. Except for the concentration and averaging period indices, each of the metrics presented in this discussion are cumulative indices, in that they increase in value as ozone exposures increase over time. Indices that give greater weight to higher concentrations correlated well with plant responses [2, 4, 6, 7]. These cumulative indices also include consideration of other varibles, including light, soil moisture, and vegetation type and/or species. Each of these indices reflects an interest and effort to incorporate biologically-relevant factors and processes into the index.

Screening of oil sands naphthenic acids by UV-Vis absorption and fluorescence emission spectrophotometry

Year of Publication: 2008

Abstract:
Oil sands extracted naphthenic acids fractions are known to contain impurities with various levels of unsaturation and aromaticity. These constituents contain functional groups that absorb ultraviolet-visible wavelength (UV-Vis) radiation and give intense florescence emission in contrast to the fully saturated alicyclic naphthenic acids. UV-Vis absorption and fluorescence emission spectrophotometry are presented here as inexpensive and quick screening methods that the detection of chromophoric surrogate compounds that serve as an internal standard for the indirect analysis of oil sands naphthenic acids. The method detection limit for the screening techniques was approximately 1 mg/L with an observed linear range of 1–100 mg/L. The precision of measurements was generally within 10% r.s.d. There was generally good agreement (within 20% r.s.d) for isotherm parameters from non-linear fitting of Langmuir, BET and Freundlich models for sorption of Athabasca oil sands naphthenic acid mixtures to activated carbon samples determined by UV-Vis absorption, fluorescence emission spectroscopy, and conventional direct injection electrospray ionization mass spectrometry.

Seasonal movements of radio tagged fish, upper Athabasca River, August, 1992 to March, 1993

Authors Clayton, T., & McLeod C.
Year of Publication: 1994

Abstract:
Report of a study to obtain information on the movements of fish species (bull trout (Salvelinus confluentus), mountain whitefish (Prosopium williamsoni), burbot (Lota lota)) in the upper reaches of the Athabasca River and to obtain data on location of critical habitats (spawning, overwintering) and feasibility of monitoring movements during low flow, under-ice overwintering periods.

Seasonal patterns of forage selection by wapiti (Cervus elaphus L.) in relation to land reclamation

Authors Fargey, P. J.
Year of Publication: 1988

Abstract:
A quantitative study of the preferences of wapiti for plant species used in land reclamation using captive wapiti to measure selection of 14 grasses and 4 legumes during winter, spring and summer seasons. Study site was located in a meadow belonging to Athabasca Ranch, near Hinton, Alberta.

Seasonal physical chemical and algal changes in five rivers flowing through the oil sands region of Alberta, Canada

Year of Publication: 1984

Abstract:
Seasonal studies concentrating upon physical and chemical parameters and the epilithic algal community were conducted at specific sites in five tributary rivers flowing through the oil sands region of northeastern Alberta, Canada into the Athabasca River. Numerically cyanophycean algae (Lyngbya aerugineo-caerulea, Phormidium sp., Calothrix braunii, Nostoc spp. and Anabaena affinis) dominated followed by diatoms (Achnanthes lanceolata, Cocconeis pediculus, Cocconeis placentula, Epithemia sorex, Epithemia turgida, Gomphonema acuminatum, Gomphonema longiceps v. subclavata, Gomphonema olivaceum, Nitzschia fonticola, Nitzschia palea, Synedra rumpens, and Synedra ulna). One exception was the Hangingstone River where chlorophycean algae (Stigeoclonium pachydermum and Cladophora glomerata) were next in importance to the cyanophytes. Seasonal fluctuations in algal species and numbers were influenced by a myriad of interacting parameters. Physically disruptive forces (current velocity and discharge) appeared more important than dissolved nutrients. They were also responsible for affecting the chemical composition of the water itself.

Seasonal sulphur biogeochemistry of oil sands composite tailings undergoing fen reclamation

Year of Publication: 2012

Abstract:
The Athabasca oil sands produce 20% of Canada’s oil, which in turn creates trillions of cubic meters of waste. The Alberta government mandates that oil sands land be reclaimed to its natural state after mining has occurred. Syncrude Canada is currently creating a novel freshwater fen on top of a composite tailings (CT) deposit as a pilot large-scale reclamation project. CT are both microbially and sulfur rich, in addition, the fen could be a potential source of labile organics and sulfate reducing bacteria which could further stimulate sulfur cycling by microorganisms with the potential to stimulate H2S(g) generation, a health and safety concern. Therefore, this thesis examines three main research questions regarding this H2S production within the Sandhill reclamation fen: 1) Is H2S generation widespread within the porewaters of the CT and sand cap of the developing Sandhill Fen reclamation project? 2) Do microbial metabolisms capable of metabolizing Fe and S linked to H2S generation occur within CT and sand cap of the developing Sandhill Fen? and 3) Will seasonality and ongoing fen construction impact H2S generation? Field and experimental results herein discuss potential microbial and abiotic metabolisms and pathways that effect sulfur and iron cycling that could affect hydrogen sulfide generation within the composite tailings and developing fen during three seasonal sampling campaigns from June 2010 to July 2011. Results indicate that detectable H2S(aq) occurred in the fen porewaters during each sampling campaign, with a trend of increasing H2S(aq) concentrations as construction of the fen progressed. Further, enrichment results indicate that microbial sulfur and iron redox reactions are likely affecting the H2S(aq) generation. Experimental microcosm results indicate that the CT may contain unstable sulfur species that can contribute to H2S(aq) generation and sequestration in the CT as pyrite. Additionally, the evolution of the Sandhill Fen changed the microbial communities that were present in situ as well as shifted dominance of species type in environmental microbial enrichments. The putative function of these bacteria show a shift from autotrophy to increased heterotrophic metabolisms as the fen is being constructed, suggesting the addition of labile organic substrates from the peat and woody debris are both changing the dominant metabolisms and well as increasing microbial diversity to the underlying CT and sand cap of Sandhill Fen. Results of this thesis established widespread microbial Fe and S metabolisms within CT for the first time and indicated that fen reclamation will alter microbial activity with implications for S cycling within CT. Although this thesis covers a short sampling time frame, it is clear that H2S(aq) generation is an important factor to consider during large scale CT reclamation. While microorganisms are present and could be impacting Fe and S cycling, the CT materials should be investigated further in regards to their potential for H2S(aq) generation. More consideration should be given to inhibiting H2S(aq) generation or supporting FeS formation within the reclamation fen.

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