Title | Adsorption of single-ring model naphthenic acid from oil sands tailings pond water using petroleum coke-derived activated carbon |
Publication Type | Thesis |
Year of Publication | 2013 |
Authors | Sarkar, B. |
Pagination | 124 pages |
Publisher | University of Toronto Department of Chemical Engineering and Applied Chemistry |
Place Published | Toronto, Ontario. |
Publication Language | eng |
Keywords | coke, laboratory, naphthenic acids, tailings water, wastewater, wastewater treatment |
Abstract | Petroleum coke-derived activated carbons were prepared and used for the adsorptive removal of a single-ring naphthenic acid (NA) from synthetic oil sands tailings pond water (TPW). The overall adsorption process was found to be intra-particle diffusion-controlled. The Weber-Morris intra-particle diffusion rate constants decreased from 7.43 to 1.23 mg/g min 0.5 after activated carbon was post-oxidized with oxygen, suggesting a hindering effect of oxygen surface groups. The Freundlich model fit of the equilibrium adsorption isotherms and the small negative ΔHo pointed to a physisorption-dominated process and the importance of specific surface area. It was estimated that about 2.7 g/L of basic CO2 -activated carbon is needed to reduce NA concentration from 120 mg/L to 2.5 mg/L (~98% removal) in synthetic TPW. However, equilibrium adsorption capacity was found to vary significantly after oxygen or nitrogen groups were introduced onto the surface. Therefore, there is a potential for enhanced adsorption by chemical functionalization of carbon. |
URL | http://search.proquest.com/docview/1501950473 |
Active Link | |
Group | OSEMB |
Citation Key | 51385 |