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TitleAdsorption of single-ring model naphthenic acid from oil sands tailings pond water using petroleum coke-derived activated carbon
Publication TypeThesis
Year of Publication2013
AuthorsSarkar, B.
Pagination124 pages
PublisherUniversity of Toronto Department of Chemical Engineering and Applied Chemistry
Place PublishedToronto, Ontario.
Publication Languageeng
Keywordscoke, laboratory, naphthenic acids, tailings water, wastewater, wastewater treatment
Abstract

Petroleum coke-derived activated carbons were prepared and used for the adsorptive removal of a single-ring naphthenic acid (NA) from synthetic oil sands tailings pond water (TPW). The overall adsorption process was found to be intra-particle diffusion-controlled. The Weber-Morris intra-particle diffusion rate constants decreased from 7.43 to 1.23 mg/g min 0.5 after activated carbon was post-oxidized with oxygen, suggesting a hindering effect of oxygen surface groups. The Freundlich model fit of the equilibrium adsorption isotherms and the small negative ΔHo pointed to a physisorption-dominated process and the importance of specific surface area. It was estimated that about 2.7 g/L of basic CO2 -activated carbon is needed to reduce NA concentration from 120 mg/L to 2.5 mg/L (~98% removal) in synthetic TPW. However, equilibrium adsorption capacity was found to vary significantly after oxygen or nitrogen groups were introduced onto the surface. Therefore, there is a potential for enhanced adsorption by chemical functionalization of carbon.

URLhttp://search.proquest.com/docview/1501950473
Active Link

http://www.worldcat.org/oclc/5571610147

Group

OSEMB

Citation Key51385

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